Advances in chemical recycling of polyethylene terephthalate (PET) via hydrolysis: A comprehensive review

IF 7.4 2区 化学 Q1 POLYMER SCIENCE Polymer Degradation and Stability Pub Date : 2025-04-01 Epub Date: 2025-02-06 DOI:10.1016/j.polymdegradstab.2025.111246
Luqman Umdagas , Rafael Orozco , Kieran Heeley , William Thom , Bushra Al-Duri
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Abstract

The increasing accumulation of waste Polyethylene Terephthalate (PET) presents a critical environmental challenge. Despite significant efforts, traditional mechanical recycling methods for PET face numerous limitations, leading to exploring alternative recycling approaches. This review explores various chemical recycling techniques for PET, focusing on neutral hydrolysis as a promising method for achieving a sustainable, closed-loop recycling system. Unlike organic solvent-based methods, hydrolysis effectively processes heterogeneous PET waste streams, including copolyesters, offering the direct recovery of terephthalic acid (TPA), the primary monomer in the PET industry. Drawing upon established research and recent advancements, this review underscores the potential of hydrolysis to play a pivotal role in advancing a circular economy for PET, thereby offering a sustainable and effective solution to plastic waste management.
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聚对苯二甲酸乙二醇酯(PET)水解化学回收研究进展综述
聚对苯二甲酸乙二醇酯(PET)废物的日益积累提出了一个严峻的环境挑战。尽管付出了巨大的努力,传统的PET机械回收方法面临着许多限制,导致探索替代回收方法。本综述探讨了PET的各种化学回收技术,重点介绍了中性水解作为实现可持续闭环回收系统的有前途的方法。与基于有机溶剂的方法不同,水解有效地处理包括共聚酯在内的异质PET废物流,直接回收PET工业中的主要单体对苯二甲酸(TPA)。根据已有的研究和最新进展,本综述强调了水解在推进PET循环经济中发挥关键作用的潜力,从而为塑料废物管理提供了可持续和有效的解决方案。
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来源期刊
Polymer Degradation and Stability
Polymer Degradation and Stability 化学-高分子科学
CiteScore
10.10
自引率
10.20%
发文量
325
审稿时长
23 days
期刊介绍: Polymer Degradation and Stability deals with the degradation reactions and their control which are a major preoccupation of practitioners of the many and diverse aspects of modern polymer technology. Deteriorative reactions occur during processing, when polymers are subjected to heat, oxygen and mechanical stress, and during the useful life of the materials when oxygen and sunlight are the most important degradative agencies. In more specialised applications, degradation may be induced by high energy radiation, ozone, atmospheric pollutants, mechanical stress, biological action, hydrolysis and many other influences. The mechanisms of these reactions and stabilisation processes must be understood if the technology and application of polymers are to continue to advance. The reporting of investigations of this kind is therefore a major function of this journal. However there are also new developments in polymer technology in which degradation processes find positive applications. For example, photodegradable plastics are now available, the recycling of polymeric products will become increasingly important, degradation and combustion studies are involved in the definition of the fire hazards which are associated with polymeric materials and the microelectronics industry is vitally dependent upon polymer degradation in the manufacture of its circuitry. Polymer properties may also be improved by processes like curing and grafting, the chemistry of which can be closely related to that which causes physical deterioration in other circumstances.
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