Growth of CuO rods on kanthal coil via direct heating for photocatalytic degradation of rhodamine B

Environmental Surfaces and Interfaces Pub Date : 2025-12-01 Epub Date: 2025-02-06 DOI:10.1016/j.esi.2025.01.004
Chee Meng Koe , Swee-Yong Pung , Sumiyyah Sabar , Anwar Ul-Hamid , Wai Kian Tan
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Abstract

This study introduces a novel direct heating (DH) method for immobilizing Cu₂O and CuO nanomaterials onto kanthal coils, offering a scalable and efficient approach to photocatalyst synthesis. The coil achieved 100 % surface coverage within 4–8 min heating duration. Both the Cu₂O and CuO phases are present, and each has a narrow band gap, making them effective reductive photocatalysts. The CuO/coil prepared at 40 W heating power for 8 minutes exhibited Cu₂O particles (1666.67 ± 727.78 nm) and CuO rods (77.77 ± 19.08 nm in diameter), achieving a 21.01 % degradation efficiency for RhB dye under UV light. Despite agglomeration of Cu₂O particles limiting active sites, this method demonstrates simplicity and rapid synthesis compared to conventional techniques. Reusability tests revealed a decline in removal efficiency to 13.24 % after three cycles, attributed to photocatalyst detachment and dye accumulation on active sites. Addressing these challenges with improved adhesion and surface optimization could enhance long-term performance. The DH method shows strong potential for industrial wastewater treatment, offering a cost-effective and scalable solution for degrading organic pollutants.
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直接加热法在kanthal线圈上生长CuO棒光催化降解罗丹明B
本研究介绍了一种新型的直接加热(DH)方法将cu₂O和CuO纳米材料固定在kanthal线圈上,为光催化剂合成提供了一种可扩展和高效的方法。线圈在4-8 分钟加热时间内达到100% %表面覆盖率。Cu₂O相和CuO相均存在,且各具有窄带隙,使其成为有效的还原性光催化剂。措/线圈准备40 W 热力 8分钟表现出铜₂O粒子(1666.67 ±727.78  海里)和措棒(77.77 ±19.08  nm直径),实现21.01 %在紫外光照射下RhB染料的降解效率。尽管Cu₂O颗粒的聚集限制了活性位点,但与传统技术相比,该方法具有简单性和快速合成性。可重用性测试表明,由于光催化剂脱落和活性位点上的染料积累,三次循环后去除效率下降至13.24 %。通过改善附着力和表面优化来解决这些挑战,可以提高长期性能。DH法在工业废水处理方面显示出强大的潜力,为降解有机污染物提供了一种具有成本效益和可扩展的解决方案。
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