Improving CO2 resistance in high-temperature humidity sensors using LaFeO3 sensing electrodes

IF 3.7 1区 化学 Q1 CHEMISTRY, ANALYTICAL Sensors and Actuators B: Chemical Pub Date : 2025-05-15 Epub Date: 2025-02-12 DOI:10.1016/j.snb.2025.137423
Ying Qian , Jie Zou , Xiaoqing Jiang , Jie Wang , Juan Zhou , Chu Cheng , Xin Zhang , Wenming He , Qinghui Jin , Jiawen Jian
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Abstract

Yttria-stabilized zirconia (YSZ)-based amperometric humidity sensors are highly promising for in situ detection of high-temperature flue ducts due to their excellent stability and durability under extreme conditions. However, selectivity remains challenging due to the co-electrolysis of H2O and CO2, as these compounds have similar electrolysis voltages. In this study, LaFeO3 is proposed as a sensing electrode to reduce CO2 electrolysis and improve selectivity in amperometric humidity sensors. Analysis indicates that the improved selectivity is likely due to LaFeO3’s lower electrochemical activity. Furthermore, the proposed sensor exhibits good repeatability and acceptable long-term stability for high-temperature humidity detection.
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利用LaFeO3传感电极提高高温湿度传感器的CO2电阻
基于钇稳定氧化锆(YSZ)的安培湿度传感器由于其在极端条件下的优异稳定性和耐用性,在高温烟道的原位检测中非常有前途。然而,由于H2O和CO2的共电解,选择性仍然具有挑战性,因为这些化合物具有相似的电解电压。在本研究中,LaFeO3被提出作为传感电极,以减少CO2电解,提高安培湿度传感器的选择性。分析表明,选择性的提高可能是由于LaFeO3的电化学活性较低。此外,该传感器在高温湿度检测中具有良好的重复性和可接受的长期稳定性。
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阿拉丁
Fe2O3
来源期刊
Sensors and Actuators B: Chemical
Sensors and Actuators B: Chemical 工程技术-电化学
CiteScore
14.60
自引率
11.90%
发文量
1776
审稿时长
3.2 months
期刊介绍: Sensors & Actuators, B: Chemical is an international journal focused on the research and development of chemical transducers. It covers chemical sensors and biosensors, chemical actuators, and analytical microsystems. The journal is interdisciplinary, aiming to publish original works showcasing substantial advancements beyond the current state of the art in these fields, with practical applicability to solving meaningful analytical problems. Review articles are accepted by invitation from an Editor of the journal.
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