Experiment and mechanism of explosion suppression thermal properties of multicomponent powder

IF 3.5 2区 化学 Q2 CHEMISTRY, ANALYTICAL Thermochimica Acta Pub Date : 2025-04-01 Epub Date: 2025-02-09 DOI:10.1016/j.tca.2025.179953
Rongkun Pan , Chensheng Wang , Qingsheng Zhang , Chenzhuo Song , Chang Lu , Ligang Zheng , Bei Pei , Lei Chen
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Abstract

In this paper, staged thermal characteristic experiments were conducted on commonly used powder explosion suppressants using a high-precision C600 microcalorimeter. The thermal decomposition process was divided into three stages, and a comprehensive analysis was carried out on the thermal flow curves, dHF, initial heat flow value H0, minimum heat flow value Hmin, characteristic points, and heat absorption amount Q of twelve powder explosion suppressants, including attapulgite and montmorillonite. The results indicate that carbamide has the smallest minimum heat flow value Hmin during powder thermal decomposition, while CaCO3 has the largest minimum heat flow value Hmin. Carbamide exhibited the highest overall heat absorption amount, while NaCl showed the lowest overall heat absorption amount. The mechanism of inhibiting methane explosion with different powder suppressors was analyzed by comparing the pyrolysis experiment results. The conclusions of this study can serve as a theoretical foundation for the rational selection of powder explosion suppressors, enhancing their utilization rate, and improving their explosion suppression effectiveness.
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多组分粉末抑爆热性能实验及机理研究
本文采用高精度C600微热量计对常用的粉末状抑爆剂进行了分阶段热特性实验。将热分解过程分为3个阶段,对凹凸棒土、蒙脱土等12种粉状抑爆剂的热流曲线、dHF、初始热流值H0、最小热流值Hmin、特征点、吸热量Q进行了综合分析。结果表明:在粉末热分解过程中,尿素的最小热流值Hmin最小,CaCO3的最小热流值Hmin最大;尿素的总吸热量最大,NaCl的总吸热量最小。通过对比热解实验结果,分析了不同抑粉剂抑制甲烷爆炸的机理。研究结论可为合理选用粉状抑爆剂,提高其利用率,提高其抑爆效果提供理论依据。
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来源期刊
Thermochimica Acta
Thermochimica Acta 化学-分析化学
CiteScore
6.50
自引率
8.60%
发文量
210
审稿时长
40 days
期刊介绍: Thermochimica Acta publishes original research contributions covering all aspects of thermoanalytical and calorimetric methods and their application to experimental chemistry, physics, biology and engineering. The journal aims to span the whole range from fundamental research to practical application. The journal focuses on the research that advances physical and analytical science of thermal phenomena. Therefore, the manuscripts are expected to provide important insights into the thermal phenomena studied or to propose significant improvements of analytical or computational techniques employed in thermal studies. Manuscripts that report the results of routine thermal measurements are not suitable for publication in Thermochimica Acta. The journal particularly welcomes papers from newly emerging areas as well as from the traditional strength areas: - New and improved instrumentation and methods - Thermal properties and behavior of materials - Kinetics of thermally stimulated processes
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