Simultaneously improving strength and ductility of carbon nanotube (CNT)-reinforced aluminum matrix composites by embedding CNTs inside matrix grains

IF 14.2 1区 材料科学 Q1 ENGINEERING, MULTIDISCIPLINARY Composites Part B: Engineering Pub Date : 2025-05-01 Epub Date: 2025-02-10 DOI:10.1016/j.compositesb.2025.112240
Lin Cao , Biao Chen , Jie Wan , Jianghua Shen , Katsuyoshi Kondoh , Shufeng Li , Jinshan Li
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Abstract

The inadequate ductility of high-strength aluminum (Al) matrix composites (AMCs) reinforced with carbon nanotubes (CNTs) greatly limits their engineering applications. Here, we report a strategy to improve the ductility of CNTs/Al composites with increased tensile strength by embedding CNTs into matrix grains. Through a modified-ball-milling-involved powder metallurgy process, two kinds of AMCs were fabricated, one with most CNTs dispersed inside grains (IG) and the other one with most CNTs at boundaries between grains (BG). A reference composite with more randomly dispersed CNTs was also fabricated by conventional ball milling. Results showed that the IG-structured composites with different CNT contents had both higher tensile strength and ductility compared with the BG composites and the reference composite. This phenomenon was associated to the different interaction behaviors between matrix dislocations and the CNTs with IG or BG distribution as revealed by transmission electron microscopy. Molecular dynamic simulation clarified the microscopic interaction mechanisms between dislocations and CNTs in IG and BG structures during deformation. This study provides a new strategy for fabricating high-strength and ductile CNT-reinforced metal matrix composites.

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通过在基体晶粒中嵌入碳纳米管(CNT)增强铝基复合材料,同时提高其强度和延展性
碳纳米管增强高强度铝基复合材料的延展性不足,极大地限制了其工程应用。在这里,我们报告了一种通过在基体晶粒中嵌入碳纳米管来提高CNTs/Al复合材料延展性和抗拉强度的策略。通过改进球磨粉末冶金工艺,制备了两种碳纳米管,一种碳纳米管大部分分布在晶粒内(IG),另一种碳纳米管大部分分布在晶粒边界(BG)。采用常规球磨法制备了碳纳米管随机分散的参考复合材料。结果表明,不同碳纳米管含量的ig结构复合材料与BG复合材料和参考复合材料相比,具有更高的拉伸强度和延展性。透射电镜显示,这种现象与基体位错与具有IG或BG分布的CNTs之间不同的相互作用行为有关。分子动力学模拟阐明了变形过程中IG和BG结构中位错与碳纳米管的微观相互作用机制。本研究为制备高强度、高韧性碳纳米管增强金属基复合材料提供了新思路。
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来源期刊
Composites Part B: Engineering
Composites Part B: Engineering 工程技术-材料科学:复合
CiteScore
24.40
自引率
11.50%
发文量
784
审稿时长
21 days
期刊介绍: Composites Part B: Engineering is a journal that publishes impactful research of high quality on composite materials. This research is supported by fundamental mechanics and materials science and engineering approaches. The targeted research can cover a wide range of length scales, ranging from nano to micro and meso, and even to the full product and structure level. The journal specifically focuses on engineering applications that involve high performance composites. These applications can range from low volume and high cost to high volume and low cost composite development. The main goal of the journal is to provide a platform for the prompt publication of original and high quality research. The emphasis is on design, development, modeling, validation, and manufacturing of engineering details and concepts. The journal welcomes both basic research papers and proposals for review articles. Authors are encouraged to address challenges across various application areas. These areas include, but are not limited to, aerospace, automotive, and other surface transportation. The journal also covers energy-related applications, with a focus on renewable energy. Other application areas include infrastructure, off-shore and maritime projects, health care technology, and recreational products.
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