Inertia effects in the spatial distribution and dynamics of active particles with space-dependent activity.

IF 3.1 2区 化学 Q3 CHEMISTRY, PHYSICAL Journal of Chemical Physics Pub Date : 2025-02-14 DOI:10.1063/5.0253096
Wen-Chao Lian, Hao-Chen Yang, Wen-de Tian, Tian Hui Zhang, Kang Chen
{"title":"Inertia effects in the spatial distribution and dynamics of active particles with space-dependent activity.","authors":"Wen-Chao Lian, Hao-Chen Yang, Wen-de Tian, Tian Hui Zhang, Kang Chen","doi":"10.1063/5.0253096","DOIUrl":null,"url":null,"abstract":"<p><p>The activity of particles can be modulated by external conditions such as light irradiation. Research on active particles with spatially varying activity has demonstrated that active particles tend to accumulate in low-activity regions and form a polarity layer at the interface, directed from the high-activity to the low-activity region. Here, we investigate the distribution and dynamics of individual or an ideal gas of inertial particles in a space with alternating active and passive regions. Our findings reveal that high inertia leads to a pronounced depletion layer in the passive region. At the interface between the active and passive regions, in addition to the usual polarity layer, an adjacent anti-polarity layer forms on the active-region side. In extreme situations (narrow region width and long persistence times), the interfacial polarity layer can even reverse orientation. Dynamically, we observe long-time peaks in the velocity autocorrelation function of particles within the active region. For particles with high inertia, the peak can even exceed 1. Correspondingly, the mean squared displacement of high-inertia particles in the active region exhibits an unusual superdiffusive behavior (∼t3). In addition, kinetic temperature and pressure differences arise between the active and passive regions. The effective temperature of particles with high inertia exhibits a gradual gradient across the active region. Our study provides new insights into the behavior of inertial active particles under spatially modulated activity and lays the groundwork for further exploration of their collective behaviors when interactions are included.</p>","PeriodicalId":15313,"journal":{"name":"Journal of Chemical Physics","volume":"162 6","pages":""},"PeriodicalIF":3.1000,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Physics","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1063/5.0253096","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

Abstract

The activity of particles can be modulated by external conditions such as light irradiation. Research on active particles with spatially varying activity has demonstrated that active particles tend to accumulate in low-activity regions and form a polarity layer at the interface, directed from the high-activity to the low-activity region. Here, we investigate the distribution and dynamics of individual or an ideal gas of inertial particles in a space with alternating active and passive regions. Our findings reveal that high inertia leads to a pronounced depletion layer in the passive region. At the interface between the active and passive regions, in addition to the usual polarity layer, an adjacent anti-polarity layer forms on the active-region side. In extreme situations (narrow region width and long persistence times), the interfacial polarity layer can even reverse orientation. Dynamically, we observe long-time peaks in the velocity autocorrelation function of particles within the active region. For particles with high inertia, the peak can even exceed 1. Correspondingly, the mean squared displacement of high-inertia particles in the active region exhibits an unusual superdiffusive behavior (∼t3). In addition, kinetic temperature and pressure differences arise between the active and passive regions. The effective temperature of particles with high inertia exhibits a gradual gradient across the active region. Our study provides new insights into the behavior of inertial active particles under spatially modulated activity and lays the groundwork for further exploration of their collective behaviors when interactions are included.

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
具有空间依赖活动的活性粒子的空间分布和动力学中的惯性效应。
粒子的活性可以通过外部条件如光照射来调节。对具有空间变化活性的活性粒子的研究表明,活性粒子倾向于在低活性区聚集,并在界面处形成极性层,由高活性区指向低活性区。本文研究了惯性粒子的理想气体在有源和无源交替空间中的分布和动力学。我们的研究结果表明,高惯性导致被动区域明显的枯竭层。在主动区和被动区交界面,除了通常的极性层外,在主动区一侧还形成相邻的反极性层。在极端情况下(狭窄的区域宽度和较长的持续时间),界面极性层甚至可以反向取向。在动力学上,我们观察到活跃区内粒子的速度自相关函数出现了长时间的峰值。对于惯量较大的粒子,峰值甚至可以超过1。相应地,高惯性粒子在活动区的均方位移表现出不寻常的超扩散行为(~ t3)。此外,在主动区和被动区之间会产生动力学温度和压力差异。高惯性粒子的有效温度在活跃区呈逐渐梯度。我们的研究为惯性主动粒子在空间调制活动下的行为提供了新的见解,并为进一步探索包括相互作用在内的集体行为奠定了基础。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Journal of Chemical Physics
Journal of Chemical Physics 物理-物理:原子、分子和化学物理
CiteScore
7.40
自引率
15.90%
发文量
1615
审稿时长
2 months
期刊介绍: The Journal of Chemical Physics publishes quantitative and rigorous science of long-lasting value in methods and applications of chemical physics. The Journal also publishes brief Communications of significant new findings, Perspectives on the latest advances in the field, and Special Topic issues. The Journal focuses on innovative research in experimental and theoretical areas of chemical physics, including spectroscopy, dynamics, kinetics, statistical mechanics, and quantum mechanics. In addition, topical areas such as polymers, soft matter, materials, surfaces/interfaces, and systems of biological relevance are of increasing importance. Topical coverage includes: Theoretical Methods and Algorithms Advanced Experimental Techniques Atoms, Molecules, and Clusters Liquids, Glasses, and Crystals Surfaces, Interfaces, and Materials Polymers and Soft Matter Biological Molecules and Networks.
期刊最新文献
Fourth-order complex time-dependent Redfield theory for absorption line shapes. Clarifying NH2 + O(3P) reaction dynamics: A full-dimensional MRCI, machine-learned PES unravels high-temperature kinetics. Revisiting photoacidity using R*NH2 photoacids. Probing component segregation and anisotropy for co-deposited glasses of TCTA and Ir(ppy)3 by GIWAXS. Medium-range ordering of interfacial water at charged clay interfaces: From layering to network connectivity.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1