Inertia effects in the spatial distribution and dynamics of active particles with space-dependent activity.

IF 3.1 2区 化学 Q3 CHEMISTRY, PHYSICAL Journal of Chemical Physics Pub Date : 2025-02-14 DOI:10.1063/5.0253096
Wen-Chao Lian, Hao-Chen Yang, Wen-de Tian, Tian Hui Zhang, Kang Chen
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Abstract

The activity of particles can be modulated by external conditions such as light irradiation. Research on active particles with spatially varying activity has demonstrated that active particles tend to accumulate in low-activity regions and form a polarity layer at the interface, directed from the high-activity to the low-activity region. Here, we investigate the distribution and dynamics of individual or an ideal gas of inertial particles in a space with alternating active and passive regions. Our findings reveal that high inertia leads to a pronounced depletion layer in the passive region. At the interface between the active and passive regions, in addition to the usual polarity layer, an adjacent anti-polarity layer forms on the active-region side. In extreme situations (narrow region width and long persistence times), the interfacial polarity layer can even reverse orientation. Dynamically, we observe long-time peaks in the velocity autocorrelation function of particles within the active region. For particles with high inertia, the peak can even exceed 1. Correspondingly, the mean squared displacement of high-inertia particles in the active region exhibits an unusual superdiffusive behavior (∼t3). In addition, kinetic temperature and pressure differences arise between the active and passive regions. The effective temperature of particles with high inertia exhibits a gradual gradient across the active region. Our study provides new insights into the behavior of inertial active particles under spatially modulated activity and lays the groundwork for further exploration of their collective behaviors when interactions are included.

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来源期刊
Journal of Chemical Physics
Journal of Chemical Physics 物理-物理:原子、分子和化学物理
CiteScore
7.40
自引率
15.90%
发文量
1615
审稿时长
2 months
期刊介绍: The Journal of Chemical Physics publishes quantitative and rigorous science of long-lasting value in methods and applications of chemical physics. The Journal also publishes brief Communications of significant new findings, Perspectives on the latest advances in the field, and Special Topic issues. The Journal focuses on innovative research in experimental and theoretical areas of chemical physics, including spectroscopy, dynamics, kinetics, statistical mechanics, and quantum mechanics. In addition, topical areas such as polymers, soft matter, materials, surfaces/interfaces, and systems of biological relevance are of increasing importance. Topical coverage includes: Theoretical Methods and Algorithms Advanced Experimental Techniques Atoms, Molecules, and Clusters Liquids, Glasses, and Crystals Surfaces, Interfaces, and Materials Polymers and Soft Matter Biological Molecules and Networks.
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