GO-Enhanced MXene Sediment-Based Inks Achieve Remarkable Oxidation Resistance and High Conductivity.

Abstract

MXenes are emerging materials renowned for their exceptional conductivity, abundant functional groups, and excellent solution processability, making them highly promising as conductive-additive-free inks for flexible electronic devices. However, current preparation methods are hampered by low yields of MXene flakes so that substantial waste MXene sediments (MS) are generated. Here, we demonstrate a type of conductive ink with appropriate rheological properties, namely MG inks formulated using MS and graphene oxide (GO), for screen-printing frequency selective surface (FSS). GO facilitates interlayer interactions by covalently cross-linking with MXene flakes, resulting in a denser structure and significantly enhancing the conductivity of the best-performing MG-based ink to 849 S cm^-1. Additionally, GO serves as a binder to considerably improve the rheological properties of MS, thus enabling high-quality printing on various substrates. The close stacking of MS and GO not only improves the oxidation resistance but also maintains conductivity above 97% even after 60 days. Furthermore, the MG-based FSS produced via straightforward screen printing demonstrates excellent performance and retains its functionality after 90 days of operation. This MS-based ink formulation represents a strategy of "turning trash into treasure" and highlights the potential of MS for the next generation of electronic devices.