Structural colored fabric with superhydrophobicity by assembly SiO2@PPy composite microspheres and spraying PDMS on white fabric

IF 4.2 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Optical Materials Pub Date : 2025-04-01 Epub Date: 2025-02-16 DOI:10.1016/j.optmat.2025.116826
Xianglu Zhao , Yinchun Fang
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Abstract

In recent years, the fabrication of amorphous photonic crystals (APCs) structural colors on fabrics has become a research hotspot in the field of textile coloring. However, the preparation of APCs structural colored fabrics usually requires the use of black fabric as a substrate or the addition of black material for co-assembly, which greatly limits the practical application. In this study, SiO2@PPy composite microspheres with different particle diameters were prepared as building units and deposited on white polyester fabric pre-treated with polyacrylate (PA) by atomization to form vivid structural colors. Polydimethylsiloxane (PDMS) was used as superhydrophobic agent to treat SiO2@PPy structural colored fabrics by spraying method. The results showed that SiO2@PPy composite microspheres with different particle diameters were prepared, which can be assembled into APCs structure on white polyester fabrics, showing different vivid structural colors. The water contact angle of structural colored fabric after PDMS treatment reached greater than 150°, showing excellent superhydrophobicity to endow it with anti-fouling property. With the introduction of PA adhesive, the structural colored fabrics had good washing and abrasion colorfastness. This study provides a new strategy for developing functional structural colored fabrics on white textile substrates.

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通过组装SiO2@PPy复合微球并在白色织物上喷涂PDMS制备具有超疏水性的结构彩色织物
近年来,在织物上制备非晶光子晶体(APCs)结构色已成为纺织着色领域的研究热点。然而,制备apc结构彩色织物通常需要使用黑色织物作为基材或添加黑色材料进行共组装,这极大地限制了实际应用。在本研究中,制备了不同粒径的SiO2@PPy复合微球作为建筑单元,并将其雾化沉积在经聚丙烯酸酯(PA)预处理的白色聚酯织物上,形成生动的结构色彩。以聚二甲基硅氧烷(PDMS)为超疏水剂,采用喷雾法对SiO2@PPy结构色织物进行处理。结果表明:制备了不同粒径的SiO2@PPy复合微球,可在白色涤纶织物上组装成APCs结构,呈现出不同的生动结构色彩。结构色织物经PDMS处理后的水接触角达到大于150°,表现出优异的超疏水性,使其具有防污性能。PA胶粘剂的加入使结构色织物具有良好的耐洗、耐磨损色牢度。本研究为在白色纺织基材上开发功能性结构彩色织物提供了新的思路。
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阿拉丁
Ammonium persulfate
阿拉丁
Pyrrole
阿拉丁
Tetraethoxysilane
来源期刊
Optical Materials
Optical Materials 工程技术-材料科学:综合
CiteScore
6.60
自引率
12.80%
发文量
1265
审稿时长
38 days
期刊介绍: Optical Materials has an open access mirror journal Optical Materials: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. The purpose of Optical Materials is to provide a means of communication and technology transfer between researchers who are interested in materials for potential device applications. The journal publishes original papers and review articles on the design, synthesis, characterisation and applications of optical materials. OPTICAL MATERIALS focuses on: • Optical Properties of Material Systems; • The Materials Aspects of Optical Phenomena; • The Materials Aspects of Devices and Applications. Authors can submit separate research elements describing their data to Data in Brief and methods to Methods X.
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