Joining Inconel 718 and GRCop42: A framework for developing transition compositions to avoid cracking and brittle phase formation

IF 7.9 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials & Design Pub Date : 2025-04-01 Epub Date: 2025-02-17 DOI:10.1016/j.matdes.2025.113733
Jakub Preis , Stephanie B. Lawson , Nick Wannenmacher , Somayeh Pasebani
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Abstract

Distinct regions of high temperature strength and high thermal conductivity are required for components such as combustion chambers. Inconel 718 and GRCop42 are commonly used for such components. However, the bimetallic joining of these alloys has been shown to result in a liquid miscibility gap at the interface, which at select compositions can lead to brittle phase formation and cracking. In this work, CALPHAD modeling is used to predict regions of brittle phase formation in the Inconel 718–Ni–GRCop42 and Ni–Cu GRCop42 multi-component ternary systems, with experimental validation of the modeling provided by arc melting. Through characterization of arc melted sample microstructure combined with CALPHAD modeling, the solidification paths throughout the system are elucidated and a brittle phase and crack free compositional region is identified. Based on these results, a compositionally graded path consisting of two transition compositions is identified. Powder Laser Directed Energy Deposition is used to fabricate the Inconel 718–GRCop42 joint with the identified transition compositions, and the joint is subject to characterization in terms of composition profile, defects, grain morphology, present phases and microhardness. Results confirm the transition compositions circumvent brittle phase formation found in bimetallic Inconel 718–GRCop42 joints, thus overcoming the thermodynamic barrier of bimetallic joining.

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结合Inconel 718和GRCop42:开发过渡组合物的框架,以避免开裂和脆性相的形成
燃烧室等部件需要具有不同的高温强度和高导热性区域。这类组件通常使用Inconel 718和GRCop42。然而,这些合金的双金属连接已被证明会导致界面处的液体混溶间隙,这在特定成分下会导致脆性相的形成和开裂。在这项工作中,CALPHAD模型用于预测Inconel 718-Ni-GRCop42和Ni-Cu GRCop42多组分三元体系中的脆性相形成区域,并通过电弧熔化提供的模型进行了实验验证。通过表征电弧熔化试样的微观组织并结合CALPHAD建模,阐明了整个体系的凝固路径,确定了脆性相和无裂纹成分区域。在此基础上,确定了一条由两种过渡成分组成的成分渐变路径。采用粉末激光定向能沉积法制备了具有确定过渡成分的Inconel 718-GRCop42接头,并对接头进行了成分分布、缺陷、晶粒形貌、存在相和显微硬度的表征。结果证实,过渡成分绕过了双金属Inconel 718-GRCop42接头中脆性相的形成,从而克服了双金属连接的热力学障碍。
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来源期刊
Materials & Design
Materials & Design Engineering-Mechanical Engineering
CiteScore
14.30
自引率
7.10%
发文量
1028
审稿时长
85 days
期刊介绍: Materials and Design is a multi-disciplinary journal that publishes original research reports, review articles, and express communications. The journal focuses on studying the structure and properties of inorganic and organic materials, advancements in synthesis, processing, characterization, and testing, the design of materials and engineering systems, and their applications in technology. It aims to bring together various aspects of materials science, engineering, physics, and chemistry. The journal explores themes ranging from materials to design and aims to reveal the connections between natural and artificial materials, as well as experiment and modeling. Manuscripts submitted to Materials and Design should contain elements of discovery and surprise, as they often contribute new insights into the architecture and function of matter.
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