Side-Chain Engineering of Boron β-Dialdiminate Homopolymer for Solvent-Dependent Emission Properties

IF 4.1 3区 化学 Q2 POLYMER SCIENCE Macromolecular Rapid Communications Pub Date : 2025-02-20 DOI:10.1002/marc.202570011
Shunichiro Ito, Yuki Sakai, Kazuo Tanaka
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Abstract

Inside Front Cover: Solvent-dependent emission of boron β-dialdiminate homopolymers is achieved by enhancing the solubility contrast between their main and side chains. The triethylene glycol-decorated polymer displays stronger emission in chloroform and weaker emission in DMF, likely because of the formation of uniformly dispersed aggregates in DMF. The cover image depicts the different solvation environments resulting in dramatic changes in the luminescent behavior. More details can be found in article 2400775 by Shunichiro Ito, Yuki Sakai, and Kazuo Tanaka.

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硼β-双缩均聚物的侧链工程及其溶剂依赖性发射特性
内页封面:硼β-拨号均聚物的溶剂依赖性发射是通过增强其主链和侧链之间的溶解度对比来实现的。三甘醇修饰聚合物在氯仿中表现出较强的发射,而在DMF中表现出较弱的发射,这可能是由于在DMF中形成了均匀分散的聚集体。封面图片描绘了不同的溶剂化环境导致发光行为的巨大变化。更多细节可以在伊藤俊一、酒井由纪和田中一夫的文章2400775中找到。
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来源期刊
Macromolecular Rapid Communications
Macromolecular Rapid Communications 工程技术-高分子科学
CiteScore
7.70
自引率
6.50%
发文量
477
审稿时长
1.4 months
期刊介绍: Macromolecular Rapid Communications publishes original research in polymer science, ranging from chemistry and physics of polymers to polymers in materials science and life sciences.
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