{"title":"Effect of SnO2 doped Pt/C catalyst on the electrocatalytic oxidation of dimethyl ether","authors":"Lehong Xing, Yungui Hao, Fanxu Meng, Yutong Zhao, Yue Zuo, Chenyang Sun, Xinting Shi, Yixin Wang","doi":"10.1016/j.ijoes.2025.100975","DOIUrl":null,"url":null,"abstract":"<div><div>The influence of the SnO<sub>2</sub> proportions on the activity of Pt/C+SnO<sub>2</sub> catalysts was examined. The results verified that Pt particles were evenly spread on the carriers. The Pt/C+SnO<sub>2</sub> catalysts demonstrated better electrooxidation activity than the Pt/C. The SnO<sub>2</sub> could carrier OH<sub>ads</sub> groups. The OH<sub>ads</sub> promoted the oxidation of CO<sub>ads</sub> and released the Pt active sites. The Pt/C+SnO<sub>2</sub> catalyst with 20 % (mass) SnO<sub>2</sub> demonstrated the excellent activity and stability for Di-Methyl Ether (DME) oxidation. Excessive SnO<sub>2</sub> might hide the active sites of Pt, which would lead to the decrease of catalyst performance.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 5","pages":"Article 100975"},"PeriodicalIF":1.3000,"publicationDate":"2025-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Electrochemical Science","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1452398125000501","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0
Abstract
The influence of the SnO2 proportions on the activity of Pt/C+SnO2 catalysts was examined. The results verified that Pt particles were evenly spread on the carriers. The Pt/C+SnO2 catalysts demonstrated better electrooxidation activity than the Pt/C. The SnO2 could carrier OHads groups. The OHads promoted the oxidation of COads and released the Pt active sites. The Pt/C+SnO2 catalyst with 20 % (mass) SnO2 demonstrated the excellent activity and stability for Di-Methyl Ether (DME) oxidation. Excessive SnO2 might hide the active sites of Pt, which would lead to the decrease of catalyst performance.
期刊介绍：
International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
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