Optimising slow pyrolysis parameters to enhance biochar European hazelnut shell as a biobased asphalt modifier

Abstract

This paper evaluated the impact of operational conditions during slow pyrolysis on the physicochemical and antioxidant properties of biochar derived from European hazelnut shells (BH), with the aim of assessing its potential as a modifier for asphalt binder. The study employed a 2² factorial design with a central point, using pyrolysis temperature (300 °C, 425 °C, and 550 °C) and residence time (1, 2, and 3 h) as study factors to produce BH. Firstly, the chemical, physical and antioxidant properties of European hazelnut shell (HS) and BH samples were compared in terms of their chemical composition, microscopic-morphology, and antioxidant capacity. Additionally, the thermal behaviour of HS was analysed. Asphalt binders were blended with 5% biochar (w/w) to assess particle distribution using confocal laser microscopy. Functional groups were also evaluated through Fourier-transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS). The results conclude that the operational conditions of slow pyrolysis significantly affect the chemical composition of biochar from European hazelnut shells, influencing the functional groups present on the asphalt surface. These conditions also influence the microstructure, increasing porosity and rugosity at higher temperatures and longer residence times. HS exhibited high antioxidant capacity, retaining up to 40% of it in the biochar when pyrolyzed at 300 °C for 1 h. Confocal laser microscopy showed uniform distribution of biochar in the asphalt binder. FT-IR and XPS tests revealed chemical interactions between the biochar and binder, characterized by bonds involving C, O, and H, particularly in biochar pyrolyzed at 300 °C and 550 °C for 1 h. The results of this study demonstrate that biochar derived from the slow pyrolysis of European hazelnut shell has the potential to be used as a bio-additive for the development of more sustainable asphalt roads.