Synergistic studies on stilbazolium derivative crystal with a 4-ethylbenzaldehyde donor group for nonlinear optical systems

IF 2.8 4区工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Journal of Materials Science: Materials in Electronics Pub Date : 2025-02-25 DOI:10.1007/s10854-025-14416-8

L. Poornima, Ravi Shanker Babu, S. Kalainathan

{"title":"Synergistic studies on stilbazolium derivative crystal with a 4-ethylbenzaldehyde donor group for nonlinear optical systems","authors":"L. Poornima, Ravi Shanker Babu, S. Kalainathan","doi":"10.1007/s10854-025-14416-8","DOIUrl":null,"url":null,"abstract":"<div><p>Materials with favorable nonlinear optical properties receive more attention in advanced optical technology. This study aims to design, synthesize, and characterize a novel single crystal with exceptional third-order nonlinear optical (NLO) properties. Utilizing the solvent evaporation method a single crystal of 1-methyl-2[2-(4-ethylphenyl)vinyl]pyridinium iodide (EMPI) was obtained with high crystallinity. The crystal structure of the EMPI was determined through Single Crystal X-ray diffraction (SCXRD), confirming its atomic arrangement and its purity was verified using the CHN elemental analysis. Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared (FT-IR) spectroscopy confirmed the molecular composition (C<sub>16</sub>H<sub>18</sub>) and functional groups of the EMPI. Hirshfeld surface analysis was employed to elucidate the intermolecular interactions in the EMPI crystal. The optical characteristics of the EMPI crystal were evaluated through the UV-Vis-NIR spectroscopy and Photoluminescence (PL) analysis, revealing its remarkable 80% transparency in the visible range and suitability for green light-emitting diodes. AFM and etching analysis affirmed that EMPI crystal has a smooth surface with fewer dislocations. The Z-Scan analysis demonstrates the third-order nonlinear optical performance and the optical limiting capabilities of the EMPI crystal, highlighting its potential as a key material for advancing optoelectronic devices and optical protection systems.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"36 6","pages":""},"PeriodicalIF":2.8000,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Science: Materials in Electronics","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10854-025-14416-8","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}

引用次数: 0

Abstract

Materials with favorable nonlinear optical properties receive more attention in advanced optical technology. This study aims to design, synthesize, and characterize a novel single crystal with exceptional third-order nonlinear optical (NLO) properties. Utilizing the solvent evaporation method a single crystal of 1-methyl-2[2-(4-ethylphenyl)vinyl]pyridinium iodide (EMPI) was obtained with high crystallinity. The crystal structure of the EMPI was determined through Single Crystal X-ray diffraction (SCXRD), confirming its atomic arrangement and its purity was verified using the CHN elemental analysis. Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared (FT-IR) spectroscopy confirmed the molecular composition (C₁₆H₁₈) and functional groups of the EMPI. Hirshfeld surface analysis was employed to elucidate the intermolecular interactions in the EMPI crystal. The optical characteristics of the EMPI crystal were evaluated through the UV-Vis-NIR spectroscopy and Photoluminescence (PL) analysis, revealing its remarkable 80% transparency in the visible range and suitability for green light-emitting diodes. AFM and etching analysis affirmed that EMPI crystal has a smooth surface with fewer dislocations. The Z-Scan analysis demonstrates the third-order nonlinear optical performance and the optical limiting capabilities of the EMPI crystal, highlighting its potential as a key material for advancing optoelectronic devices and optical protection systems.

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

非线性光学系统中4-乙基苯甲醛二苯唑衍生物晶体的协同作用研究

具有良好非线性光学特性的材料在先进光学技术中受到越来越多的关注。本研究旨在设计、合成并表征一种具有三阶非线性光学（NLO）特性的新型单晶。采用溶剂蒸发法制备了高结晶度的1-甲基-2[2-（4-乙基苯基）乙烯基]碘化吡啶（EMPI）单晶。通过单晶x射线衍射（SCXRD）测定了EMPI的晶体结构，确定了其原子排列，并用CHN元素分析验证了其纯度。核磁共振（NMR）和傅里叶变换红外光谱（FT-IR）证实了EMPI的分子组成（C16H18）和官能团。采用Hirshfeld表面分析方法分析了EMPI晶体中的分子间相互作用。通过紫外-可见-近红外光谱和光致发光（PL）分析对EMPI晶体的光学特性进行了评价，表明其在可见光范围内具有80%的透明度，适合绿色发光二极管。原子力显微镜和蚀刻分析证实了EMPI晶体表面光滑，位错少。Z-Scan分析显示了EMPI晶体的三阶非线性光学性能和光学限制能力，突出了其作为先进光电器件和光学保护系统关键材料的潜力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文去求助

来源期刊

Journal of Materials Science: Materials in Electronics 工程技术-材料科学：综合

CiteScore

5.00

自引率

7.10%

发文量

1931

审稿时长

2 months

期刊介绍： The Journal of Materials Science: Materials in Electronics is an established refereed companion to the Journal of Materials Science. It publishes papers on materials and their applications in modern electronics, covering the ground between fundamental science, such as semiconductor physics, and work concerned specifically with applications. It explores the growth and preparation of new materials, as well as their processing, fabrication, bonding and encapsulation, together with the reliability, failure analysis, quality assurance and characterization related to the whole range of applications in electronics. The Journal presents papers in newly developing fields such as low dimensional structures and devices, optoelectronics including III-V compounds, glasses and linear/non-linear crystal materials and lasers, high Tc superconductors, conducting polymers, thick film materials and new contact technologies, as well as the established electronics device and circuit materials.