Ultra-flexible silicon foils with seamless detachability: The effect of porous multilayered structures prepared through modulated electrolyte composition

IF 6.9 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Applied Surface Science Pub Date : 2025-06-30 Epub Date: 2025-02-25 DOI:10.1016/j.apsusc.2025.162759
C. Sanchez-Perez , P. Rivas-Lazaro , E. García-Tabarés , I. García
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Abstract

A comprehensive evaluation of the effect and limitations of variable current density and electrolyte composition on layer porosity and microstructure changes of porous silicon (pSi) multilayer stacks is reported. Following these results, the development and optimization of a four-layer stack architecture is reported through addition of super-low porosity layers (SLPL) on a low/high porosity layer (LPL/HLP) stack. Thermal treatment of these structures achieved excellent top and bottom surface reconstruction to form sintered porous silicon (SPS) detachable foils, enabling direct foil separation using cello tape from a smooth and specular parent substrate without the need to cut or damage it.

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具有无缝可拆卸性的超柔性硅箔:通过调节电解质成分制备的多孔多层结构的影响
本文综合评价了不同电流密度和电解质组成对多孔硅(pSi)多层堆叠层孔隙率和微观结构变化的影响和局限性。根据这些结果,通过在低/高孔隙层(LPL/HLP)叠层上添加超低孔隙层(SLPL),开发和优化了四层叠层结构。这些结构的热处理实现了优异的顶部和底部表面重建,形成烧结多孔硅(SPS)可拆卸箔,可以使用大提琴带从光滑和镜面母基板上直接分离箔,而无需切割或损坏它。
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来源期刊
Applied Surface Science
Applied Surface Science 工程技术-材料科学:膜
CiteScore
12.50
自引率
7.50%
发文量
3393
审稿时长
67 days
期刊介绍: Applied Surface Science covers topics contributing to a better understanding of surfaces, interfaces, nanostructures and their applications. The journal is concerned with scientific research on the atomic and molecular level of material properties determined with specific surface analytical techniques and/or computational methods, as well as the processing of such structures.
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