Chitosan-Lemongrass Essential Oil on Paperboard for Active Food Packaging Applications.

IF 4.9 3区 工程技术 Q1 POLYMER SCIENCE Polymers Pub Date : 2025-02-11 DOI:10.3390/polym17040473
Mariangela de Fátima Silva, Julia Vaz Ernesto, Alessandra Rigo Rinaldi, Ana Paula Reis Noletto, Patricia Santos Lopes, Rosemary Aparecida de Carvalho, Vitor Augusto Dos Santos Garcia, Cristiana Maria Pedroso Yoshida
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Abstract

An active film-forming solution of chitosan and lemongrass essential oil was applied as a coating on paperboard, forming an alternative and sustainable packaging material for food applications. The active paper-film systems were characterized by color parameters, thermogravimetric analyses, contact angles, Fourier transform infrared spectroscopy, X-ray diffraction, mechanical properties, and cytotoxicity. The active coated paperboard was homogeneous and yellowish in appearance. The tensile strength (transverse and longitudinal directions) was directly influenced by increasing the number of layers of the chitosan-lemongrass active coating. The oil concentration significantly affected the Taber stiffness (transverse direction). The active coatings with higher concentrations of lemongrass essential oil altered the thermal stability of the coated paperboard. The contact angle values were characteristic of hydrophobic materials. The coated systems presented three characteristic peaks in the X-ray diffraction analysis-2θ = 16.5°, 22.9°, and 29.8°-and an amorphous halo at 18.9°. The cytotoxicity analysis of the active material (1:40:5) indicated potential reductions in the lemongrass essential oil content to maintain cell viability while ensuring insecticidal efficacy, supporting its safe use as food-contact active packaging. In this way, the active packaging system based on a chitosan coating containing lemongrass essential oil on paperboard could be a type of efficient active material packaging which is safe in contact with food and sustainable for the environment.

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壳聚糖-柠檬草精油在活性食品包装纸板上的应用。
将壳聚糖和柠檬草精油的活性成膜液涂在纸板上,形成了一种可替代的可持续食品包装材料。通过颜色参数、热重分析、接触角、傅里叶变换红外光谱、x射线衍射、力学性能和细胞毒性对活性纸膜体系进行了表征。活性涂布纸板均匀,外观呈淡黄色。壳聚糖-香茅活性膜层数的增加直接影响材料的横向和纵向抗拉强度。油液浓度对塔伯刚度(横向)有显著影响。添加高浓度香茅精油的活性涂料改变了涂布纸板的热稳定性。接触角值具有疏水材料的特征。在x射线衍射分析中,涂层体系呈现出3个特征峰-2θ = 16.5°,22.9°和29.8°,并在18.9°处有一个无定形晕。活性物质(1:40:5)的细胞毒性分析表明,在保证杀虫效果的同时,柠檬草精油含量可能会减少,以保持细胞活力,支持其作为食品接触活性包装的安全使用。因此,在纸板上涂覆含有柠檬草精油的壳聚糖活性包装系统是一种与食品接触安全、对环境可持续发展的高效活性材料包装。
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来源期刊
Polymers
Polymers POLYMER SCIENCE-
CiteScore
8.00
自引率
16.00%
发文量
4697
审稿时长
1.3 months
期刊介绍: Polymers (ISSN 2073-4360) is an international, open access journal of polymer science. It publishes research papers, short communications and review papers. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Polymers provides an interdisciplinary forum for publishing papers which advance the fields of (i) polymerization methods, (ii) theory, simulation, and modeling, (iii) understanding of new physical phenomena, (iv) advances in characterization techniques, and (v) harnessing of self-assembly and biological strategies for producing complex multifunctional structures.
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