Thermodynamic prediction of alloying element distribution in magnesium matrix composites

IF 13.8 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Journal of Magnesium and Alloys Pub Date : 2025-09-01 Epub Date: 2025-02-27 DOI:10.1016/j.jma.2025.01.022
Xiwei Zhou , Yuan Yuan , Tingting Liu , Tao Chen , Jun Wang , Ligang Zhang , Liang Wu , Aitao Tang , Xianhua Chen , Andrej Atrens , Fusheng Pan
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Abstract

The effect of alloying elements on the properties of magnesium (Mg) matrix composites is significant. The distribution of alloy elements between the matrix and the reinforcements plays a pivotal role in the element selection and compositional design of Mg-based metal matrix composite. This work used thermodynamics to study the equilibrium distribution coefficients of the 40 elements X (Be, Ca, Zn, Sn, REs, etc.) in the Mg-Ti and Mg-Zr systems at 573 K, 773 K and 973 K. In addition, the binary solution enthalpies were evaluated using the Miedema model to predict the bonding tendency of the element X with Mg, Ti and Zr. These research outputs provide valuable data and theoretical reference for Mg-alloy design and optimization.

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镁基复合材料中合金元素分布的热力学预测
合金元素对镁基复合材料的性能影响显著。合金元素在基体和增强体之间的分布对镁基金属基复合材料的元素选择和成分设计起着至关重要的作用。本文利用热力学方法研究了Mg-Ti和Mg-Zr体系中40种元素(Be、Ca、Zn、Sn、REs等)在573 K、773 K和973 K下的平衡分布系数。此外,利用Miedema模型评估了二元溶液焓,预测了元素X与Mg、Ti和Zr的成键趋势。这些研究成果为镁合金的设计和优化提供了有价值的数据和理论参考。
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来源期刊
Journal of Magnesium and Alloys
Journal of Magnesium and Alloys Engineering-Mechanics of Materials
CiteScore
20.20
自引率
14.80%
发文量
52
审稿时长
59 days
期刊介绍: The Journal of Magnesium and Alloys serves as a global platform for both theoretical and experimental studies in magnesium science and engineering. It welcomes submissions investigating various scientific and engineering factors impacting the metallurgy, processing, microstructure, properties, and applications of magnesium and alloys. The journal covers all aspects of magnesium and alloy research, including raw materials, alloy casting, extrusion and deformation, corrosion and surface treatment, joining and machining, simulation and modeling, microstructure evolution and mechanical properties, new alloy development, magnesium-based composites, bio-materials and energy materials, applications, and recycling.
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