Er microalloying significantly refines precipitates to simultaneously promote the strength and ductility of Mg-Gd-Y-Zn-Zr alloy

IF 7.9 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials & Design Pub Date : 2025-04-01 Epub Date: 2025-02-22 DOI:10.1016/j.matdes.2025.113759
Qian Zhang, Fulin Wang, Jian Zeng, Fenghua Wang, Shuai Dong, Li Jin, Jie Dong
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Abstract

The contradiction between the strength and ductility of magnesium (Mg) alloys has become a theoretical obstacle and technical bottleneck in their research. The preparation technology of ultrafine grains/nanocrystals relying on severe plastic deformation deviates from actual industrial production, therefore alloying is currently a more practical choice. This work simultaneously promoted the strength and ductility of Mg-Gd-Y-Zn-Zr alloy by adding a trace amount of Er element (0.5 wt%). Er microalloying has little effect on grain size, texture, morphology and content of long-period stacking ordered (LPSO) structure, but significantly promotes aging precipitation, thereby substantially increasing the number density of β’ and reducing its size. The significantly refined β’ makes calculations based on the Orowan bypass mechanism less accurate, and more consideration should be given to linking the synchronous improvement of strength and ductility with the dislocation-shearing mechanism.

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Er微合金化显著细化了Mg-Gd-Y-Zn-Zr合金的析出相,同时提高了合金的强度和塑性
镁合金的强度与塑性矛盾已成为镁合金研究的理论障碍和技术瓶颈。依赖于剧烈塑性变形的超细颗粒/纳米晶制备技术与实际工业生产相背离,因此合金化是目前较为现实的选择。本工作通过添加微量的Er元素(0.5 wt%)同时提高了Mg-Gd-Y-Zn-Zr合金的强度和延展性。Er微合金化对长周期有序堆积(LPSO)组织的晶粒尺寸、织构、形貌和含量影响不大,但显著促进时效析出,从而大幅提高β′的数量密度,减小β′的尺寸。显著细化的β′使得基于Orowan旁路机制的计算精度降低,应更多地考虑将强度和延性的同步提高与位错-剪切机制联系起来。
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来源期刊
Materials & Design
Materials & Design Engineering-Mechanical Engineering
CiteScore
14.30
自引率
7.10%
发文量
1028
审稿时长
85 days
期刊介绍: Materials and Design is a multi-disciplinary journal that publishes original research reports, review articles, and express communications. The journal focuses on studying the structure and properties of inorganic and organic materials, advancements in synthesis, processing, characterization, and testing, the design of materials and engineering systems, and their applications in technology. It aims to bring together various aspects of materials science, engineering, physics, and chemistry. The journal explores themes ranging from materials to design and aims to reveal the connections between natural and artificial materials, as well as experiment and modeling. Manuscripts submitted to Materials and Design should contain elements of discovery and surprise, as they often contribute new insights into the architecture and function of matter.
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