Stable and high color purity light-emitting diodes of free-standing perovskite single crystal film

IF 2.7 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Letters Pub Date : 2025-06-15 Epub Date: 2025-03-04 DOI:10.1016/j.matlet.2025.138274
Wei Zhang , Yifei Wang , Hengyang Xiang , Yongshu Wang , Fan Wu , Zhongchao Bai , Qiang Zhang , Yuan Chen
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Abstract

An antisolvent engineering strategy was proposed to prevent the solvent corrosion phenomenon, the specific type and ratio of antisolvents was demonstrated could effectively decrease the surface defect density. Consequently, the CsPbBr3 perovskite single crystal films (PSCF) present well optical and electrical properties. Accordingly, the light emitting diode based on bared PSCF that without only surface passivation and interface modification achieved high performance. Over 10,000 brightness and external quantum efficiency about 1.3 % were achieved. Moreover, the electroluminescence peak located at 521 nm showed a narrow half peak width of 18 nm, which well meets the display requirements of NTSC. The device also presents good stability, the T50 has reached 2 and 37 h at the brightness of 1000 cd/cm2 and 100 cd/cm2, respectively.

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独立钙钛矿单晶薄膜的稳定、高色纯度发光二极管
提出了一种防止溶剂腐蚀现象的抗溶剂工程策略,并证明了特定类型和比例的抗溶剂可以有效降低表面缺陷密度。因此,CsPbBr3钙钛矿单晶膜(PSCF)具有良好的光学和电学性能。因此,基于裸PSCF的发光二极管在没有表面钝化和界面修饰的情况下获得了高性能。达到了10000以上的亮度和约1.3%的外量子效率。电致发光峰位于521 nm处,呈现出18 nm的窄半峰宽,很好地满足了NTSC的显示要求。该器件还具有良好的稳定性,在1000 cd/cm2和100 cd/cm2的亮度下,T50分别达到2和37小时。
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来源期刊
Materials Letters
Materials Letters 工程技术-材料科学:综合
CiteScore
5.60
自引率
3.30%
发文量
1948
审稿时长
50 days
期刊介绍: Materials Letters has an open access mirror journal Materials Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. Materials Letters is dedicated to publishing novel, cutting edge reports of broad interest to the materials community. The journal provides a forum for materials scientists and engineers, physicists, and chemists to rapidly communicate on the most important topics in the field of materials. Contributions include, but are not limited to, a variety of topics such as: • Materials - Metals and alloys, amorphous solids, ceramics, composites, polymers, semiconductors • Applications - Structural, opto-electronic, magnetic, medical, MEMS, sensors, smart • Characterization - Analytical, microscopy, scanning probes, nanoscopic, optical, electrical, magnetic, acoustic, spectroscopic, diffraction • Novel Materials - Micro and nanostructures (nanowires, nanotubes, nanoparticles), nanocomposites, thin films, superlattices, quantum dots. • Processing - Crystal growth, thin film processing, sol-gel processing, mechanical processing, assembly, nanocrystalline processing. • Properties - Mechanical, magnetic, optical, electrical, ferroelectric, thermal, interfacial, transport, thermodynamic • Synthesis - Quenching, solid state, solidification, solution synthesis, vapor deposition, high pressure, explosive
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