Cover Feature: The Competition Between Cation-Anion and Cation-Triglyme Interaction in Solvate Ionic Liquids Probed by Far Infrared Spectroscopy and Molecular Dynamics Simulations (ChemPhysChem 5/2025)
Jule Kristin Philipp, Koichi Fumino, Andreas Appelhagen, Dietmar Paschek, Ralf Ludwig
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引用次数: 0
Abstract
The Cover Feature illustrates the contact and solvent-separated ion pairs present in mixtures of lithium bis(trifluoromethanesulfonyl)imide ([Li][NTf2]) and triglyme (G3), often called solvate ionic liquids. In their Research Article (DOI: 10.1002/cphc.202400991), R. Ludwig and co-workers relate how they used far infrared spectroscopy to probe cation–anion and cation–triglyme interactions depending on the salt concentration. Molecular dynamics simulations provided a detailed molecular picture of the complexes formed in this promising electrolyte system.
期刊介绍:
ChemPhysChem is one of the leading chemistry/physics interdisciplinary journals (ISI Impact Factor 2018: 3.077) for physical chemistry and chemical physics. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
ChemPhysChem is an international source for important primary and critical secondary information across the whole field of physical chemistry and chemical physics. It integrates this wide and flourishing field ranging from Solid State and Soft-Matter Research, Electro- and Photochemistry, Femtochemistry and Nanotechnology, Complex Systems, Single-Molecule Research, Clusters and Colloids, Catalysis and Surface Science, Biophysics and Physical Biochemistry, Atmospheric and Environmental Chemistry, and many more topics. ChemPhysChem is peer-reviewed.