Solvation and Related Thermochemical Behavior of DL-Valine in Aqueous Univalent Electrolytes for Temperatures from 288.15 K to 323.15 K

IF 2.5 4区工程技术 Q3 CHEMISTRY, PHYSICAL International Journal of Thermophysics Pub Date : 2025-03-10 DOI:10.1007/s10765-025-03534-4

Simanta Kundu, Jit Chakraborty, Perwez Alam, Avishek Saha, Sintu Ganai, Puspal Mukherjee, Kalachand Mahali, Sanjay Roy

{"title":"Solvation and Related Thermochemical Behavior of DL-Valine in Aqueous Univalent Electrolytes for Temperatures from 288.15 K to 323.15 K","authors":"Simanta Kundu, Jit Chakraborty, Perwez Alam, Avishek Saha, Sintu Ganai, Puspal Mukherjee, Kalachand Mahali, Sanjay Roy","doi":"10.1007/s10765-025-03534-4","DOIUrl":null,"url":null,"abstract":"<div><p>This research chiefly surveys the changes in the solubility and thermochemical behavior of DL-valine due to the existence of univalent electrolytes—namely, sodium bromide and potassium bromide—in an aqueous medium. The experiments were conducted in the temperature range from 288.15 K to 323.15 K using gravimetric analysis. Both bromides show salting-in effect which in turn implicates a large impact on the solubility of the investigated amino acid in the reaction medium. The values of the calculated thermodynamic parameters provide evidence towards the stability of the ions in the solution. The stability is mainly governed by the noncovalent processes, such as dissolution (and its stability) and short-range interactions (e.g., acid–base, solvent–solvent, and solute–solvent). This study provides insights into the molecular interactions and energetics that influence the solvation of the amino acid under diverse experimental conditions.</p><h3>Graphical Abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":598,"journal":{"name":"International Journal of Thermophysics","volume":"46 5","pages":""},"PeriodicalIF":2.5000,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Thermophysics","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10765-025-03534-4","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

Abstract

This research chiefly surveys the changes in the solubility and thermochemical behavior of DL-valine due to the existence of univalent electrolytes—namely, sodium bromide and potassium bromide—in an aqueous medium. The experiments were conducted in the temperature range from 288.15 K to 323.15 K using gravimetric analysis. Both bromides show salting-in effect which in turn implicates a large impact on the solubility of the investigated amino acid in the reaction medium. The values of the calculated thermodynamic parameters provide evidence towards the stability of the ions in the solution. The stability is mainly governed by the noncovalent processes, such as dissolution (and its stability) and short-range interactions (e.g., acid–base, solvent–solvent, and solute–solvent). This study provides insights into the molecular interactions and energetics that influence the solvation of the amino acid under diverse experimental conditions.

Graphical Abstract

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

求助全文

约1分钟内获得全文去求助

来源期刊

International Journal of Thermophysics 物理-力学

CiteScore

4.10

自引率

9.10%

发文量

179

审稿时长

5 months

期刊介绍： International Journal of Thermophysics serves as an international medium for the publication of papers in thermophysics, assisting both generators and users of thermophysical properties data. This distinguished journal publishes both experimental and theoretical papers on thermophysical properties of matter in the liquid, gaseous, and solid states (including soft matter, biofluids, and nano- and bio-materials), on instrumentation and techniques leading to their measurement, and on computer studies of model and related systems. Studies in all ranges of temperature, pressure, wavelength, and other relevant variables are included.