Influence of medium polyurethane coating on mechanical, wear, and corrosion performance of a galvanised steel sheet

Sneha Roy, Swarup Kumar Ghosh
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Abstract

Colour-coated steel, also known as pre-coated steel or pre-painted steel, has become a material of choice across diverse industries due to its aesthetic allure and practical advantages. The present study delves into the coated low-carbon (∼ 0.04 wt%) steel's mechanical properties, abrasive wear behaviour, and electrochemical corrosion resistance. The excellent combination of tensile properties (340 MPa YS, 347 MPa UTS and 33 % total elongation) ensures structural integrity and load-bearing capacity. The robust polyurethane (PU) coating demonstrates good abrasion resistance through its lower Taber wear index (0.022). Nano-scratch tests further reinforce the coating's ability to withstand frictional forces, with minimal signs of observed wear. The results of electrochemical corrosion indicate that the coating provides exceptional protection against deterioration, even in harsh environments with 5 % NaCl solution for 600 h. Both OCP and Tafel plots illustrate lower corrosion rates in PU-coated steels owing to lower potential and inhibited reactions. The Icorr of the coated steel was 265 µA/cm2, which is substantially lower than that of the uncoated steel of 1864 µA, indicating much lesser corrosion. The more positive Ecorr (-637 mV) value for the coated steel also denotes better corrosion resistance coupled with robustness. Nyquist plots validate higher charge transfer resistance, which portrays the coating as a strong impediment against chloride. This significantly increases the lifespan of coated steel under extreme conditions. The corrosion tests confirmed long-term durability, with negligible rust or coating degradation signs. Hence, colour-coated steel emerges as a true champion, combining good mechanical properties, wear resistance, and corrosion protection.
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中等聚氨酯涂层对镀锌钢板机械、磨损和腐蚀性能的影响
彩涂钢,也被称为预涂钢或预涂钢,由于其美学吸引力和实用优势,已成为各种行业的首选材料。目前的研究深入研究了涂层低碳(~ 0.04 wt%)钢的机械性能、磨料磨损性能和电化学耐腐蚀性。优异的拉伸性能组合(340 MPa YS, 347 MPa UTS和33 %的总伸长率)确保了结构的完整性和承载能力。聚氨酯(PU)涂层具有较低的Taber磨损指数(0.022),具有良好的耐磨性。纳米划痕测试进一步增强了涂层承受摩擦力的能力,同时观察到的磨损迹象最小。电化学腐蚀结果表明,即使在5 % NaCl溶液600 h的恶劣环境中,涂层也能提供出色的防腐蚀保护。OCP和Tafel图都表明,由于电位较低和反应抑制,pu涂层钢的腐蚀速率较低。涂层钢的Icorr为265 µA/cm2,明显低于未涂层钢的1864µA,表明其腐蚀程度较低。涂层钢的Ecorr值越高(-637 mV),也表明涂层钢的耐腐蚀性越好,同时具有鲁棒性。奈奎斯特图验证了更高的电荷转移电阻,这表明涂层对氯化物具有很强的阻碍作用。这大大增加了涂层钢在极端条件下的使用寿命。腐蚀测试证实了长期耐用性,几乎没有生锈或涂层退化的迹象。因此,结合良好的机械性能、耐磨性和防腐蚀性能,彩色涂层钢成为真正的冠军。
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