Youhua ZUO , Rong LI , Licheng XU , Junfeng HUA , Siyu HAO , Jing XIE , Lixin XU , Mingfu YE , Chao WAN
{"title":"Investigation of Ni0.4Cu0.6/POM photocatalytic hydrogen generation efficiency using ammonia borane hydrolysis","authors":"Youhua ZUO , Rong LI , Licheng XU , Junfeng HUA , Siyu HAO , Jing XIE , Lixin XU , Mingfu YE , Chao WAN","doi":"10.1016/S1872-5813(24)60478-0","DOIUrl":null,"url":null,"abstract":"<div><div>Ni and Cu were used as active components in the impregnation reduction process to create the Ni<sub>0.4</sub>Cu<sub>0.6</sub>/POM catalyst after supported cyclophosphazene polymer (POM) was manufactured by solvothermal technique. Hydrogen was produced through photocatalytic hydrolysis of ammonia borane using the catalyst. The catalysts were evaluated using a variety of techniques, including TEM, XRD, XPS, FT-IR, UV-vis DRS, PL, and EIS. The Ni<sub>0.4</sub>Cu<sub>0.6</sub>/POM catalyst exhibits a stable spherical particle structure, according to the experimental results. After 20 cycles, the catalytic reaction still exhibits good catalytic activity with a TOF value of 1461.0 h<sup>–1</sup> under 298 K and light circumstances, which is 1.6 times that under non-light conditions.</div></div>","PeriodicalId":15956,"journal":{"name":"燃料化学学报","volume":"53 3","pages":"Pages 360-370"},"PeriodicalIF":0.0000,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"燃料化学学报","FirstCategoryId":"1087","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1872581324604780","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Energy","Score":null,"Total":0}
引用次数: 0
Abstract
Ni and Cu were used as active components in the impregnation reduction process to create the Ni0.4Cu0.6/POM catalyst after supported cyclophosphazene polymer (POM) was manufactured by solvothermal technique. Hydrogen was produced through photocatalytic hydrolysis of ammonia borane using the catalyst. The catalysts were evaluated using a variety of techniques, including TEM, XRD, XPS, FT-IR, UV-vis DRS, PL, and EIS. The Ni0.4Cu0.6/POM catalyst exhibits a stable spherical particle structure, according to the experimental results. After 20 cycles, the catalytic reaction still exhibits good catalytic activity with a TOF value of 1461.0 h–1 under 298 K and light circumstances, which is 1.6 times that under non-light conditions.
期刊介绍：
Journal of Fuel Chemistry and Technology (Ranliao Huaxue Xuebao) is a Chinese Academy of Sciences(CAS) journal started in 1956, sponsored by the Chinese Chemical Society and the Institute of Coal Chemistry, Chinese Academy of Sciences(CAS). The journal is published bimonthly by Science Press in China and widely distributed in about 20 countries. Journal of Fuel Chemistry and Technology publishes reports of both basic and applied research in the chemistry and chemical engineering of many energy sources, including that involved in the nature, processing and utilization of coal, petroleum, oil shale, natural gas, biomass and synfuels, as well as related subjects of increasing interest such as C1 chemistry, pollutions control and new catalytic materials. Types of publications include original research articles, short communications, research notes and reviews. Both domestic and international contributors are welcome. Manuscripts written in Chinese or English will be accepted. Additional English titles, abstracts and key words should be included in Chinese manuscripts. All manuscripts are subject to critical review by the editorial committee, which is composed of about 10 foreign and 50 Chinese experts in fuel science. Journal of Fuel Chemistry and Technology has been a source of primary research work in fuel chemistry as a Chinese core scientific periodical.
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