Guangyuan Liang, Sheng Yang, Chao Wu, Yang Liu, Yi Zhao, Liang Huang, Shaowei Zhang, Shi Xue Dou, Hongfang Du, Dandan Cui, Liangxu Lin
{"title":"Advancing C–C Coupling of Electrocatalytic CO2 Reduction Reaction for C2+ Products","authors":"Guangyuan Liang, Sheng Yang, Chao Wu, Yang Liu, Yi Zhao, Liang Huang, Shaowei Zhang, Shi Xue Dou, Hongfang Du, Dandan Cui, Liangxu Lin","doi":"10.1039/d4ta09210d","DOIUrl":null,"url":null,"abstract":"The production of multicarbon (C2+) products through electrocatalytic CO2 reduction reaction (CO2RR) is crucial to addressing global environmental challenges and advancing sustainable energy solutions. However, efficiently producing these high-value chemicals via C–C coupling reactions is a significant challenge. This requires catalysts with optimized surface configurations and electronic properties capable of breaking the scaling relations among various intermediates. In this report, we introduce the fundamentals of electrocatalytic CO2RR and the mechanism of C–C coupling. We examine the effects of catalytic surface interactions with key intermediates and reaction pathways, and discuss emerging strategies for enhancing C–C coupling reactions toward C2+ products. Despite varieties of these strategies, we summarize direct clues for the proper design of the catalyst for the electrocatalytic CO2RR towards C2+ products, aiming to provide valuable insights to broad readers in the field.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"41 1","pages":""},"PeriodicalIF":10.7000,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Chemistry A","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1039/d4ta09210d","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The production of multicarbon (C2+) products through electrocatalytic CO2 reduction reaction (CO2RR) is crucial to addressing global environmental challenges and advancing sustainable energy solutions. However, efficiently producing these high-value chemicals via C–C coupling reactions is a significant challenge. This requires catalysts with optimized surface configurations and electronic properties capable of breaking the scaling relations among various intermediates. In this report, we introduce the fundamentals of electrocatalytic CO2RR and the mechanism of C–C coupling. We examine the effects of catalytic surface interactions with key intermediates and reaction pathways, and discuss emerging strategies for enhancing C–C coupling reactions toward C2+ products. Despite varieties of these strategies, we summarize direct clues for the proper design of the catalyst for the electrocatalytic CO2RR towards C2+ products, aiming to provide valuable insights to broad readers in the field.
期刊介绍：
The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.
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