Calcium carbide residue for clay stabilisation: mechanical and microstructural properties

Abstract

Calcium carbide residue (CCR), a calcium-rich industrial waste, shows promise in improving mechanical properties of weak soils when used alone or in combination with pozzolanic materials and alkaline activators. This study comprehensively investigated the mechanical performance and stabilisation mechanism of CCR, CCR-fly ash, and alkaline-activated CCR-fly ash on kaolin clay, aiming to clarify their differences in mechanisms, identify their limitations, and promote effective application. The contribution of CCR, fly ash, alkaline activator, and initial water content of soil on enhancing soil strength was quantitively assessed through signal-to-noise ratio and analysis of variance (ANOVA) based on the Taguchi method. The stabilisation mechanism of different CCR-based materials was investigated by assessing the morphological and mineralogical features of stabilised samples. Taguchi analysis revealed that the development of soil strength was primarily influenced by initial water content in the early curing stage, while the contribution of fly ash became larger over time. Variation in CCR content had a limited effect on soil strength across all curing periods, as indicated by low contribution values and low statistical significance in ANOVA. The microstructural analyses revealed a low degree of formation of C-S-H and C-A-H gels in soil stabilised with CCR alone and CCR combined with fly ash, while alkaline activated CCR-fly ash stabilised soil exhibited the coexistence of C-A-S-H and N-A-S-H gels. Taguchi superposition model was effectively used to estimate compressive strength results and supported the determination of suitable CCR-based materials for specific strength requirements.