Advances in photodegradation of organic pollutants using polymer supported Fenton catalysts

Tetrahedron Green Chem Pub Date : 2025-06-01 Epub Date: 2025-03-12 DOI:10.1016/j.tgchem.2025.100073
Shajahan Rubina , Kareem A. Feby , Saithalavi Anas
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Abstract

Photodegradation of organic pollutants in wastewater is an ideal process for reducing environmental pollution, as it harnesses light energy to break down harmful compounds into safer byproducts. Supported catalysts play a crucial role in this process as they increase the stability and reusability of the photocatalysts, enhance light absorption, and improve degradation efficiency by providing a larger surface area for the reaction. This certainly improves the sustainability and effectiveness of the contaminated water treatment. This review article provides a comprehensive overview of various polymer-supported Fenton catalysts for the photodegradation of organic compounds in wastewater treatment. The discussion is structured based on the type of polymer such as polystyrene, polyacrylonitrile, resins, Nafion and other miscellaneous polymers employed as suitable solid support for Fenton catalysts. Key aspects of each category of these supported catalysts are explored, including their preparation methods, structural characteristics, and catalytic performance in degrading pollutants under different conditions. The review also focuses on the recent challenges and gaps in this area of research in terms of catalyst stability, reusability, and efficiency under varying environmental conditions. By consolidating the existing knowledge on the title topic, this article serves as a valuable resource for researchers and practitioners, offering insights into the potential of polymer-supported Fenton catalysts and directing toward more effective and sustainable photocatalytic systems for wastewater treatment.

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聚合物负载Fenton催化剂光降解有机污染物研究进展
光降解废水中的有机污染物是减少环境污染的理想方法,因为它利用光能将有害化合物分解成更安全的副产品。负载型催化剂在这一过程中起着至关重要的作用,因为它们增加了光催化剂的稳定性和可重复使用性,增强了光吸收,并通过为反应提供更大的表面积来提高降解效率。这无疑提高了污水处理的可持续性和有效性。本文综述了各种聚合物负载Fenton催化剂在废水处理中光降解有机化合物的研究进展。讨论是基于聚合物的类型,如聚苯乙烯,聚丙烯腈,树脂,Nafion和其他杂项聚合物被用来作为合适的固体载体的芬顿催化剂。探讨了每一类负载催化剂的关键方面,包括它们的制备方法、结构特征和在不同条件下降解污染物的催化性能。综述还重点介绍了在不同环境条件下催化剂稳定性、可重复使用性和效率方面该领域研究的最新挑战和差距。通过巩固关于标题主题的现有知识,本文为研究人员和实践者提供了宝贵的资源,提供了对聚合物负载Fenton催化剂潜力的见解,并指导了更有效和可持续的废水处理光催化系统。
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