Synthesis and performance evaluation of an efficient nano-particle viscosity reducer for enhanced heavy oil recovery in Pingfangwang Oilfield

IF 5.2 2区 化学 Q2 CHEMISTRY, PHYSICAL Journal of Molecular Liquids Pub Date : 2025-05-15 Epub Date: 2025-03-12 DOI:10.1016/j.molliq.2025.127381
Wenxun Zhao , Jingjing Liu , Xianhua Gao , Xuehong Qi , Pan Wang , Xiaoqiang Liu , Yue Shi , Qing You
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Abstract

Unconventional resources, such as heavy oil, have become strategic alternatives to conventional reservoirs. The Pingfangwang Oilfield, a major heavy oil production site within the Shengli Oilfield in China, contains formation oil with a viscosity of 500–800 mPa·s, an oil recovery rate of 0.2–0.3 %, and a recovery factor of 20–30 %. Given the crude oil parameters and reservoir characteristics of the Pingfangwang Oilfield, this study developed a highly efficient active nano viscosity reducer. The active nano viscosity reducer exhibited a microscopic dispersion size of ∼20 nm, with a surface enriched with long-chain alkanes and polar amide groups. Laboratory results indicated that 0.3 wt% of the active nano viscosity reducer lowered the oil–water interfacial tension to 19.65 mN/m. After treatment, the water contact angle on the core surface ranged from 135.4° to 141.2°, thereby effectively enhancing interfacial activity. In comparison with conventional surfactants and commercial nanomaterials, the active nano viscosity reducer achieved an oil film stripping efficiency of >90 %, and the viscosity reduction rate in the reservoir environment exceeded 90 %. To elucidate its viscosity reduction mechanism, a molecular simulation system was developed according to the composition of the heavy oil in the field, using GROMACS software. Simulations revealed the mechanism by which the active nano viscosity reducer reduced heavy oil viscosity. Specifically, the viscosity reducer molecules disrupted the stacking structure of asphaltene molecules, formed stronger hydrogen bonds, and effectively inserted themselves into the structure, thereby breaking the asphaltene network and lowering the viscosity. This study offered both theoretical foundation and technical support for the efficient development of heavy oil in the Pingfangwang Oilfield through the application of an active nano viscosity reducer and insights into its mechanism.
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平方旺油田稠油高效纳米降粘剂合成及性能评价
重油等非常规资源已成为常规储层的战略替代品。平方王油田是中国胜利油田稠油主产区,地层油粘度500 ~ 800 mPa·s,采收率0.2 ~ 0.3%,采收率20 ~ 30%。结合平方旺油田的原油参数和储层特征,研制了一种高效活性纳米降粘剂。活性纳米减粘剂的微观分散尺寸为~ 20 nm,表面富含长链烷烃和极性酰胺基团。实验结果表明,0.3 wt%的活性纳米降粘剂可使油水界面张力降至19.65 mN/m。处理后岩心表面的水接触角在135.4°~ 141.2°之间,有效增强了界面活性。与常规表面活性剂和商用纳米材料相比,活性纳米降粘剂的油膜剥离效率达到90%以上,在油藏环境中的降粘率超过90%。为阐明稠油降粘机理,根据油田稠油组成,利用GROMACS软件建立了稠油降粘分子模拟系统。模拟结果揭示了活性纳米降粘剂降低稠油粘度的机理。具体来说,降粘剂分子破坏了沥青质分子的堆积结构,形成了更强的氢键,并有效地插入到结构中,从而破坏了沥青质网络,降低了粘度。本研究通过研究活性纳米降粘剂的应用及其作用机理,为平方旺油田稠油高效开发提供了理论基础和技术支撑。
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来源期刊
Journal of Molecular Liquids
Journal of Molecular Liquids 化学-物理:原子、分子和化学物理
CiteScore
10.30
自引率
16.70%
发文量
2597
审稿时长
78 days
期刊介绍: The journal includes papers in the following areas: – Simple organic liquids and mixtures – Ionic liquids – Surfactant solutions (including micelles and vesicles) and liquid interfaces – Colloidal solutions and nanoparticles – Thermotropic and lyotropic liquid crystals – Ferrofluids – Water, aqueous solutions and other hydrogen-bonded liquids – Lubricants, polymer solutions and melts – Molten metals and salts – Phase transitions and critical phenomena in liquids and confined fluids – Self assembly in complex liquids.– Biomolecules in solution The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include: – Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.) – Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.) – Light scattering (Rayleigh, Brillouin, PCS, etc.) – Dielectric relaxation – X-ray and neutron scattering and diffraction. Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.
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