Wenxun Zhao , Jingjing Liu , Xianhua Gao , Xuehong Qi , Pan Wang , Xiaoqiang Liu , Yue Shi , Qing You
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引用次数: 0
Abstract
Unconventional resources, such as heavy oil, have become strategic alternatives to conventional reservoirs. The Pingfangwang Oilfield, a major heavy oil production site within the Shengli Oilfield in China, contains formation oil with a viscosity of 500–800 mPa·s, an oil recovery rate of 0.2–0.3 %, and a recovery factor of 20–30 %. Given the crude oil parameters and reservoir characteristics of the Pingfangwang Oilfield, this study developed a highly efficient active nano viscosity reducer. The active nano viscosity reducer exhibited a microscopic dispersion size of ∼20 nm, with a surface enriched with long-chain alkanes and polar amide groups. Laboratory results indicated that 0.3 wt% of the active nano viscosity reducer lowered the oil–water interfacial tension to 19.65 mN/m. After treatment, the water contact angle on the core surface ranged from 135.4° to 141.2°, thereby effectively enhancing interfacial activity. In comparison with conventional surfactants and commercial nanomaterials, the active nano viscosity reducer achieved an oil film stripping efficiency of >90 %, and the viscosity reduction rate in the reservoir environment exceeded 90 %. To elucidate its viscosity reduction mechanism, a molecular simulation system was developed according to the composition of the heavy oil in the field, using GROMACS software. Simulations revealed the mechanism by which the active nano viscosity reducer reduced heavy oil viscosity. Specifically, the viscosity reducer molecules disrupted the stacking structure of asphaltene molecules, formed stronger hydrogen bonds, and effectively inserted themselves into the structure, thereby breaking the asphaltene network and lowering the viscosity. This study offered both theoretical foundation and technical support for the efficient development of heavy oil in the Pingfangwang Oilfield through the application of an active nano viscosity reducer and insights into its mechanism.
期刊介绍:
The journal includes papers in the following areas:
– Simple organic liquids and mixtures
– Ionic liquids
– Surfactant solutions (including micelles and vesicles) and liquid interfaces
– Colloidal solutions and nanoparticles
– Thermotropic and lyotropic liquid crystals
– Ferrofluids
– Water, aqueous solutions and other hydrogen-bonded liquids
– Lubricants, polymer solutions and melts
– Molten metals and salts
– Phase transitions and critical phenomena in liquids and confined fluids
– Self assembly in complex liquids.– Biomolecules in solution
The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include:
– Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.)
– Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.)
– Light scattering (Rayleigh, Brillouin, PCS, etc.)
– Dielectric relaxation
– X-ray and neutron scattering and diffraction.
Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.