{"title":"Local field and deformation of droplets in emulsions","authors":"Arthur Zakinyan , Ali M. Ahmed , Daria Kononenko","doi":"10.1016/j.molliq.2025.127406","DOIUrl":null,"url":null,"abstract":"<div><div>The deformation of individual liquid droplets in an applied electric or magnetic field is a traditional subject of research. Deformation processes in the system of droplets of the dispersed phase of an emulsion are of fundamental and applied interest but are currently poorly understood. Such processes must depend on the interaction of the droplets with each other. In this work, emulsions of ideal dielectric fluids in an electric field or ferrofluids in a magnetic field are considered. As a result of computer simulations and experimental studies, it is shown that the imposition of an external field on the system of droplets leads to their stretching along the field, accompanied by a slower process of formation of chain structures from droplets. At the initial stage of the system evolution, long-range interactions of polarized droplets can influence the degree of their deformation differently depending on the ratio of permeabilities of the dispersed phase and the dispersion medium. The subsequent formation of chain structures of droplets leads to the manifestation of short-range interactions of neighboring droplets in chains. These interactions, caused by the attraction of the droplets to each other, lead to the compression of the droplets in the field direction, which reduces the resulting degree of elongation of the droplets, regardless of the ratio of the properties of the droplets and the medium.</div></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":"427 ","pages":"Article 127406"},"PeriodicalIF":5.3000,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Molecular Liquids","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167732225005732","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The deformation of individual liquid droplets in an applied electric or magnetic field is a traditional subject of research. Deformation processes in the system of droplets of the dispersed phase of an emulsion are of fundamental and applied interest but are currently poorly understood. Such processes must depend on the interaction of the droplets with each other. In this work, emulsions of ideal dielectric fluids in an electric field or ferrofluids in a magnetic field are considered. As a result of computer simulations and experimental studies, it is shown that the imposition of an external field on the system of droplets leads to their stretching along the field, accompanied by a slower process of formation of chain structures from droplets. At the initial stage of the system evolution, long-range interactions of polarized droplets can influence the degree of their deformation differently depending on the ratio of permeabilities of the dispersed phase and the dispersion medium. The subsequent formation of chain structures of droplets leads to the manifestation of short-range interactions of neighboring droplets in chains. These interactions, caused by the attraction of the droplets to each other, lead to the compression of the droplets in the field direction, which reduces the resulting degree of elongation of the droplets, regardless of the ratio of the properties of the droplets and the medium.
期刊介绍:
The journal includes papers in the following areas:
– Simple organic liquids and mixtures
– Ionic liquids
– Surfactant solutions (including micelles and vesicles) and liquid interfaces
– Colloidal solutions and nanoparticles
– Thermotropic and lyotropic liquid crystals
– Ferrofluids
– Water, aqueous solutions and other hydrogen-bonded liquids
– Lubricants, polymer solutions and melts
– Molten metals and salts
– Phase transitions and critical phenomena in liquids and confined fluids
– Self assembly in complex liquids.– Biomolecules in solution
The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include:
– Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.)
– Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.)
– Light scattering (Rayleigh, Brillouin, PCS, etc.)
– Dielectric relaxation
– X-ray and neutron scattering and diffraction.
Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.