Bridge-Oxygen Bond: An Active Group for Energy Electrocatalysis

IF 19 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Advanced Functional Materials Pub Date : 2025-03-20 DOI:10.1002/adfm.202500351
Nana Zhang, Zilan Zhang, Siwei Yan, Rui Zhang, Pengfei Yin, Xiwen Du, Hui Liu
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Abstract

Energy electrocatalytic reactions such as hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, nitrogen reduction reaction, carbon reduction reaction, etc., are important reactions to solve the current energy shortage and the increasing environmental problems. Developing novel and efficient catalyts for these reactions has become an essential and urgent issue. Catalysts incorporating bridge-oxygen bond have received increasing attention due to their superior conductivity and stability, which are favorable for optimizing the reaction mechanism and improving the reaction kinetics. This paper provides a comprehensive review encompassing the concept of bridge-oxygen bond, the means of characterization, the activity in energy electrocatalysis and the effect on the catalytic performance. Through this review, it is expected to furnish a valuable reference for the rational design of catalysts featuring a bridge-oxygen structure across diverse energy electrocatalytic reactions.

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桥-氧键:能量电催化的活性基团
能量电催化反应如析氢反应、析氧反应、氧还原反应、氮还原反应、碳还原反应等,是解决当前能源短缺和日益严峻的环境问题的重要反应。为这些反应开发新型高效的催化剂已成为一个重要而紧迫的问题。含桥氧键催化剂由于其优异的导电性和稳定性,有利于优化反应机理和改善反应动力学,越来越受到人们的关注。本文从桥氧键的概念、表征方法、能量电催化活性及其对催化性能的影响等方面进行了综述。通过这一综述,期望为合理设计跨不同能量电催化反应的桥氧结构催化剂提供有价值的参考。
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来源期刊
Advanced Functional Materials
Advanced Functional Materials 工程技术-材料科学:综合
CiteScore
29.50
自引率
4.20%
发文量
2086
审稿时长
2.1 months
期刊介绍: Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week. Advanced Functional Materials is known for its rapid and fair peer review, quality content, and high impact, making it the first choice of the international materials science community.
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