Effect of mass loading on the capacitive performance of sustainable porous carbon

IF 2.8 4区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Journal of Materials Science: Materials in Electronics Pub Date : 2025-03-29 DOI:10.1007/s10854-025-14670-w
Devu Bindhu, B. S. Lekshmi, M. Simi, C. O. Sreekala, Vishnu Vardhan Palem, A. Santhy
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Abstract

The accelerated energy consumption and its impacts on our lives have led to the development of various efficient and sustainable energy storage devices. The bioderived materials are viable, cost-effective, and sustainable and hence a versatile material in fabricating energy storage devices, especially for supercapacitors. Herein a porous 3D honeycomb-like carbon is derived from the biomaterial coconut rachis which was used for the fabrication of electrodes for a supercapacitor with chitosan as the binder. A high surface area of 1,630.67 m2/g and a pore size distribution ranging from 1.5 nm to 5 nm were observed, confirming the material’s suitability for energy storage applications. Electrochemical tests revealed a maximum specific capacitance of 199 F/g at a current density of 0.62 A/g, with stable cycle life retention of 94–95% after 10,000 cycles. The optimized mass loading of the electrodes demonstrated superior performance, highlighting the potential of coconut rachis-derived carbon as an environmentally friendly and cost-effective alternative for supercapacitor applications. These findings suggest that the developed material holds promise for future energy storage systems that prioritize both performance and sustainability.

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质量负载对可持续多孔碳电容性能的影响
能源消耗的加速及其对我们生活的影响促使了各种高效、可持续的储能装置的发展。生物衍生材料是可行的,具有成本效益和可持续性的,因此是制造能量存储设备,特别是超级电容器的通用材料。在此,多孔的三维蜂窝状碳来源于生物材料椰子轴,椰子轴用于制造超级电容器的电极,壳聚糖作为粘合剂。该材料的表面积高达1630.67 m2/g,孔径分布在1.5 nm ~ 5 nm之间,证实了该材料适合储能应用。电化学测试表明,在0.62 a /g电流密度下,该材料的最大比电容为199 F/g,循环10000次后,其稳定的循环寿命保持率为94-95%。优化后的电极质量负载表现出卓越的性能,突出了椰子树衍生碳作为超级电容器应用的环保和成本效益替代品的潜力。这些发现表明,开发的材料有望在未来的储能系统中优先考虑性能和可持续性。
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来源期刊
Journal of Materials Science: Materials in Electronics
Journal of Materials Science: Materials in Electronics 工程技术-材料科学:综合
CiteScore
5.00
自引率
7.10%
发文量
1931
审稿时长
2 months
期刊介绍: The Journal of Materials Science: Materials in Electronics is an established refereed companion to the Journal of Materials Science. It publishes papers on materials and their applications in modern electronics, covering the ground between fundamental science, such as semiconductor physics, and work concerned specifically with applications. It explores the growth and preparation of new materials, as well as their processing, fabrication, bonding and encapsulation, together with the reliability, failure analysis, quality assurance and characterization related to the whole range of applications in electronics. The Journal presents papers in newly developing fields such as low dimensional structures and devices, optoelectronics including III-V compounds, glasses and linear/non-linear crystal materials and lasers, high Tc superconductors, conducting polymers, thick film materials and new contact technologies, as well as the established electronics device and circuit materials.
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