A comparison study of the efficacy of different activated charcoals derived from Palmyra kernel shell in removing phenolic compounds

Ganeshalingm Sashikesh , Periyasamy Anushkkaran , Yadhavan Praveena , Manjceevan Arumukham , Velauthamurty Kugamoorthy , Vignarooban Kandasamy
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Abstract

Phenol is one of the most prevalent contaminants discovered in water bodies. The adsorption process is gaining popularity as a viable method of removing phenolic chemicals from contaminated aquatic resources. The elimination of phenolic chemicals using Palmyra kernel shell activated charcoal has been extensively investigated. The removal effectiveness of Palmyra kernel shell charcoal was calculated using physically, chemically (H3PO4 and NaOH) and magnetically activated Palmyra kernel shell charcoal for various amounts of phenolic components and varying adsorption durations. According to this research study, physically activated charcoal has a much higher removal efficiency than other activated charcoal. These findings show that physically activated charcoal is easily used to remove phenolic compounds from polluted water resources. Adsorption kinetics were discovered to follow a pseudo-second-order kinetic model. Freundlich, Langmuir, and Temkin isotherm models were used to interpret the experimental results. Several kinetic formulas were utilized to evaluate the adsorption kinetics of phenolic compounds using various activated charcoals derived from Palmyra kernel shells. The experimental results are consistent with the Freundlich isotherm model. All of the activated and non-activated Palmyra kernel shells absorbed the phenolic chemicals, and the value of 1/n was found to be between 0.692 to 0.869. Scanning Electron Microscopy (SEM) is a technique used to characterize the surface morphology of adsorbents before and after adsorption. FTIR analyses confirmed the presence of phenolic compound functional groups on the adsorbents.

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巴尔米拉仁壳不同活性炭去除酚类化合物效果的比较研究
苯酚是水体中最常见的污染物之一。吸附法作为一种可行的去除受污染水生资源中酚类化学物质的方法越来越受欢迎。利用巴尔米拉核壳活性炭去除酚类化学物质已被广泛研究。采用物理、化学(H3PO4和NaOH)和磁活化的巴尔米拉仁壳活性炭对不同数量的酚类成分和不同吸附时间的去除效果进行了计算。根据本研究,物理活性炭比其他活性炭具有更高的去除效率。这些研究结果表明,物理活性炭很容易用于去除污染水资源中的酚类化合物。吸附动力学遵循伪二级动力学模型。采用Freundlich、Langmuir和Temkin等温模型解释实验结果。采用不同的动力学公式,对不同的棕榈仁壳活性炭对酚类化合物的吸附动力学进行了评价。实验结果与Freundlich等温线模型一致。活化和非活化的巴尔米拉仁壳对酚类化学物质的吸收量均在0.692 ~ 0.869之间。扫描电子显微镜(SEM)是一种用于表征吸附剂吸附前后表面形貌的技术。红外光谱分析证实了吸附剂上存在酚类化合物官能团。
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来源期刊
Current Research in Green and Sustainable Chemistry
Current Research in Green and Sustainable Chemistry Materials Science-Materials Chemistry
CiteScore
11.20
自引率
0.00%
发文量
116
审稿时长
78 days
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