Co-precipitation synthesis of LaFe1-xAlxO3 (x = 0–0.2) on structure and electromagnetic properties

Martha Rianna , Timbangen Sembiring , Erwin Amiruddin , Perdamean Sebayang
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引用次数: 2

Abstract

The synthesis of LaFe1-xAlxO3 (x = 0–0.2) on the structure and electromagnetic properties using the co-precipitation method were evaluated. LaFe1-xAlxO3 (x = 0–0.2) materials were synthesized using lanthanum chloride and natural iron sand powders. The mixing process of precursors was held with a hotplate temperature of 60 °C. The calcination process was done at 400 °C for 2 h. Then samples were analyzed using X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Vibrating Sample Magnetometer (VSM), and CV meter. The XRD patterns result in two phases of LaFeO3 and Fe2O3. SEM images were performed that the powders are porous agglomerates. The particle size distribution is shown in the histogram that the samples are in the range of 50–500 nm, respectively. Then, the magnetic properties measurement of VSM analysis studied the substitution of Fe to Al ions decreases magnetic properties and BHmax in LaFe1-xAlxO3 (x = 0–0.2). The I-V measurements conducted the substitution of Fe to Al ions increase with a nonlinear reversal current in LaFeO3. These results show that LaFe1-xAlxO3 (x = 0–0.2) was recommended as the magnetic permanent material and perovskite material based on electromagnetic properties.

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共沉淀法合成LaFe1-xAlxO3 (x=0-0.2)的结构和电磁性能
用共沉淀法对合成LaFe1-xAlxO3 (x = 0-0.2)的结构和电磁性能进行了评价。以氯化镧和天然铁砂粉为原料合成了LaFe1-xAlxO3 (x = 0-0.2)材料。前驱体的混合过程在60℃的热板温度下进行。在400℃下煅烧2 h,然后用x射线衍射仪(XRD)、扫描电镜(SEM)、振动样品磁强计(VSM)和CV仪对样品进行分析。XRD谱图显示出LaFeO3和Fe2O3两相结构。扫描电镜(SEM)分析表明,粉末为多孔团聚体。从直方图中可以看出,样品的粒径分布范围分别在50-500 nm之间。然后,通过VSM分析研究了Fe取代Al离子对LaFe1-xAlxO3的磁性能和BHmax的降低(x = 0-0.2)。I-V测量结果表明,在LaFeO3中,随着非线性反转电流的增加,Fe离子被Al离子取代。结果表明,基于电磁性能,推荐LaFe1-xAlxO3 (x = 0-0.2)作为磁性永久材料和钙钛矿材料。
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来源期刊
Materials Science for Energy Technologies
Materials Science for Energy Technologies Materials Science-Materials Science (miscellaneous)
CiteScore
16.50
自引率
0.00%
发文量
41
审稿时长
39 days
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