HEAVY METALS CONTAMINATION AND DISTRIBUTION IN SURFACE WATER AND SEDIMENT OF THE ABOABO STREAM, AHAFO REGION, GHANA

Ebenezer Asante Boafo Brobbey, B. Koomson, F. O. Agyemang
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Abstract

Activities of illegal small-scale miners promote continual introduction of wide pollutants into the Aboabo stream. Their toxicity poses health threats to the inhabitants of Krapoo village in the Ahafo Region, Ghana. The study assesses the impacts of illegal small-scale mining activities on the water quality of the stream. Levels of physico-chemical and microbiological parameters were determined using standard methods. Samples of sediment, water and plant were acid-digested with aqua-regia. Total Arsenic and Total Cadmium were analysed using Flame Atomic Absorption Spectrophotometer (FLAAS) whiles Total Mercury was analysed using Cold Vapour Atomic Absorption Spectrophotometer (CV-AAS). Turbidity, faecal coliforms and E-coli readings exceeded permissible limit of 5NTU and 0MPN/100ml respectively by Ghana’s Environmental Protection Agency (GS 1212) and World Health Organisation (WHO). Temperature, Electrical Conductivity and pH values were within the limit of <30oC, 1500μs/cm and 6.5-85 respectively at both seasons. Total suspended solids readings at the midstream were higher than the permissible limit. However, levels of total dissolved solutes and dissolved oxygen recorded, were below the limit. The sediments were also heavily polluted with Mercury, Arsenic and Cadmium. Alchornea cordifolia, Chromolaena odorata and Spigella anthelmia growing within the stream were taken to assess their efficiency in removing the heavy metals from the stream. It was observed that the plants species had bioaccumulation factor (BF) greater than 1 for cadmium. Alchornea cordifolia was the only plant with BF greater than 1 for mercury. The plants species are potential hyper accumulators for mercury and cadmium hence are suitable for phytoremediation.
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加纳阿哈福地区ABOABO河地表水和沉积物中重金属污染及分布
非法小规模矿工的活动促使大量污染物不断进入Aboabo河。它们的毒性对加纳Ahafo地区Krapoo村的居民的健康构成威胁。该研究评估了非法小规模采矿活动对溪流水质的影响。使用标准方法测定物理化学和微生物参数的水平。用王水对沉积物、水和植物样品进行酸消化。用火焰原子吸收分光光度计(FLAAS)分析总砷和总镉,用冷蒸气原子吸收分光度计(CV-AAS)分析全汞。加纳环境保护局(GS 1212)和世界卫生组织(世界卫生组织)的浊度、粪便大肠菌群和大肠杆菌读数分别超过5NTU和0MPN/100ml的允许限值。两个季节的温度、电导率和pH值分别在<30oC、1500μs/cm和6.5-85的范围内。中游的总悬浮固体读数高于允许限值。然而,记录的总溶解溶质和溶解氧的水平低于限值。沉积物还受到汞、砷和镉的严重污染。在溪流中生长的Alchorena cordifolia、Chromolaena odorata和Spigella驱虫虫被用来评估它们从溪流中去除重金属的效率。据观察,这些植物物种对镉的生物累积因子(BF)大于1。茜草是唯一一种对汞BF大于1的植物。这些植物物种是汞和镉的潜在超级蓄积器,因此适合于植物修复。
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