Utilization of Nagarparker kaolin for the synthesis of zeolite-zsm, a value added product

IF 0.1 Q4 ENGINEERING, CHEMICAL Journal of the Pakistan Institute of Chemical Engineers Pub Date : 2021-05-25 DOI:10.54693/piche.04915
H. Mahar, S. A. Soomro, A. Memon, S. Holmes
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Abstract

Nagarparker arid zone of Pakistan. It has large deposits of Kaolin (China Clay) approximately 4.3 million tons. Crystal zeolite ZSM produced and characterized. Material ground, calcined dehydrated using ball mill, autoclave and furnace respectively due to dehydration kaolinite converted into metakaolin with a weight loss of about 3.9% and 8 M solution of Sodium hydroxide added with the ratio of 1:5 at 100 °C with vigorous stirring for 1 h. Fusion carried out at 100 °C for 1 h, sample washed 3 times to make its pH normal. Characteristic Si-O-Al, OH, Al-OH and Si-OH bands were confirmed in Fourier Transform Infrared Spectroscopy studies. Scanning Electron microscopy showed clear morphology of zeolite zsm. Xray Diffraction showed 2ÆŸ peaks and revealed orthogonal shaped crystal structure. The results show that the Nagarparker kaoling is suitable for the synthesis of Zeolite ZSM as value added Product.
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Nagararker高岭土在合成zsm沸石中的应用
巴基斯坦的Nagarparker干旱区。它有大量高岭土(中国粘土)矿床,约430万吨。ZSM晶体沸石的制备和表征。材料研磨,分别使用球磨机、高压釜和熔炉煅烧脱水,因为脱水高岭土转化为重量损失约3.9%的偏高岭土,并在100°C下以1:5的比例添加8M氢氧化钠溶液,剧烈搅拌1h。在100°C.下进行1 h的融合,样品洗涤3次以使其pH正常。傅立叶变换红外光谱研究证实了Si-O-Al、OH、Al-OH和Si-OH的特征谱带。扫描电子显微镜显示zsm沸石的形貌清晰。X射线衍射显示出2个峰,并显示出正交形状的晶体结构。结果表明,Nagarmarker高岭土适用于ZSM沸石的合成。
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