Surface Modification of AZ31B Magnesium Alloy by Anodization process

IF 0.1 Q4 ENGINEERING, CHEMICAL Journal of the Pakistan Institute of Chemical Engineers Pub Date : 2021-03-30 DOI:10.54693/piche.04912
Faraz Hussain, M. U. Manzoor, M. Kamran, Muhammad Taqi Zahid Butt
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Abstract

Magnesium alloys emerge as a new class of biomaterials in medical field especially in orthopedic applications as medical implant because of its excellent mechanical, biocompatible, bioactive and biodegradable properties. Biodegradable magnesium alloys attracted great attention of researchers to avoid implant removal surgery after healing process. The magnesium alloy samples were anodized in two different electrolyte solutions to further improve the biodegradability of the substrates. The processing time varies from 10 minutes to 40 minutes with constant voltage of 20V. coated samples were characterized with scanning electron microscopy (SEM) for surface topography and energy dispersive x-ray spectroscopy (EDX) confirmed the deposition of thick and dense oxide layers of anodized film of magnesium oxide (MgO) and magnesium hydroxide Mg(OH)2 in electrolyte 2. The results of electrochemical Impedance spectroscopy (EIS) are in a good agreement with the analyses of surface morphology. The anodic film formed by electrolyte 2 provides better biodegradability as compared to electrolyte 1.
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AZ31B镁合金阳极氧化表面改性研究
镁合金以其优异的力学性能、生物相容性、生物活性和可生物降解等特点,在医学领域尤其是医用植入体领域成为一类新的生物材料。生物可降解镁合金因其在愈合过程中可避免植入物移除手术而备受关注。镁合金样品在两种不同的电解质溶液中进行阳极处理,以进一步提高基质的生物降解性。在20V恒定电压下,处理时间为10分钟~ 40分钟。利用扫描电镜(SEM)和x射线能谱仪(EDX)对涂层样品进行了表面形貌表征,证实了电解质2中氧化镁(MgO)和氢氧化镁(OH)2的阳极氧化膜沉积了厚而致密的氧化层。电化学阻抗谱(EIS)分析结果与表面形貌分析结果吻合较好。与电解质1相比,电解质2形成的阳极膜具有更好的生物可降解性。
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