Preparation and properties of graphite/polypropylene composite material reinforced by chopped carbon fibers for proton-exchange membrane fuel cell bipolar plates

Abstract

In this work, chopped carbon fibers (CCFs) with different lengths were added to graphite/polypropylene (PP) composite materials to achieve high conductivity and flexural strength performances, which are required for use in proton exchange membrane fuel cells. The effects of CCF length (2–4 mm), CCF content (0–5 wt.%), graphite type-natural flake graphite (NFG) and synthetic graphite (SG), and graphite particle size (18–106 µm) on the graphite/PP/CCFs composites are examined. The conductivities of the composites decrease significantly with increasing CCF length above 3 wt.%. CCFs improve the composite's strength, with a maximum strength of 45.8 MPa being achieved with 5 wt.% of 4 mm long CCFs. Composite with NFG exhibits superior conductivity to the one with SG but lacks flexural strength. The NFG particle size significantly affects the conductivity of the composite at high graphite contents, with a particle diameter of 75 µm resulting in maximum conductivity. An optimal composition with 38 µm/82 wt.% NFG and 2 mm/3 wt.% CCF, electrical conductivity, and flexural strength of 189.4 S/cm and 30.2 MPa, respectively, were achieved. Also, this composite exhibited interfacial contact resistance $2.52m\Omega ·c{m}^2$ and contact angles of 111°, which showed favorable interfacial conductivity and hydrophobicity performances.