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Composite Solid Oxide/Molten Hydroxide Electrolyte for Hybrid Fuel Cells 混合燃料电池用固体氧化物/熔融氢氧化物复合电解质
IF 3.1 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-12-08 DOI: 10.1002/fuce.70037
Lamis Atwi, Armelle Ringuedé, Valérie Albin, Styliani Papadopoulou, Michel Cassir, Virginie Lair

For more than a century, alkaline electrolyzers and fuel cells (AEL and AFC) have been widely used due to their considerable power densities and lifetimes. However, AFCs encounter issues in managing liquid electrolytes, in operating at higher temperatures, and tolerating carbon dioxide. To solve these limitations a hybrid fuel cell is presented that uses a composite electrolyte containing solid oxide and molten hydroxide phases to operate at intermediate temperatures (400-600°C). These materials are particularly interesting due to their potential to reduce the operating temperature of fuel cells while maintaining high power densities and conductivities. Previous research on oxide-carbonate composites found conductivity of 0.1 S·cm−1 at 600°C. This paper focuses on the development of a new composite electrolyte based on solid oxide-molten hydroxide for hybrid fuel cells. Specifically, the hybrid system composed of samarium-doped ceria (SDC) and different hydroxides (LiOH, NaOH) was studied using a series of thermal, vibrational and electrochemical analyses in different operating conditions. A detailed examination of the electrolyte using differential scanning calorimetry was done to identify the phase transformation temperatures and the stability conditions for the hydroxide phase. A high conductivity of 0.04 S·cm− 1 was achieved with an SDC-NaOH (70-30 wt%) composite in a reducing H2 atmosphere at 400°C. Several challenges remain, particularly in the selection of new electrode materials and ensuring their long-term stability.

一个多世纪以来,碱性电解槽和燃料电池(AEL和AFC)由于其相当大的功率密度和寿命而被广泛使用。然而,afc在管理液体电解质、在较高温度下运行和耐受二氧化碳方面遇到了问题。为了解决这些限制,提出了一种混合燃料电池,该电池使用含有固体氧化物和熔融氢氧化物相的复合电解质,在中间温度(400-600°C)下工作。这些材料特别有趣,因为它们有可能降低燃料电池的工作温度,同时保持高功率密度和导电性。先前对氧化物-碳酸盐复合材料的研究发现,在600°C时电导率为0.1 S·cm−1。研究了一种新型混合燃料电池用固体氧化物-熔融氢氧化物复合电解质。具体来说,在不同的操作条件下,通过一系列的热、振动和电化学分析,研究了由掺钐铈(SDC)和不同氢氧化物(LiOH, NaOH)组成的杂化体系。用差示扫描量热法对电解液进行了详细的检查,以确定氢氧化物相的相变温度和稳定性条件。SDC-NaOH (70-30 wt%)复合材料在400℃的还原H2气氛中获得了0.04 S·cm−1的高电导率。仍然存在一些挑战,特别是在选择新的电极材料和确保其长期稳定性方面。
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引用次数: 0
Optimized MPPT Control of a Non-Isolated High-Gain Interleaved DC–DC Converter for Fuel Cell Electric Vehicles Using Hybrid Optimization Algorithm 基于混合优化算法的燃料电池汽车非隔离高增益交错DC-DC变换器最大功率优化控制
IF 3.1 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-12-05 DOI: 10.1002/fuce.70034
K. Umadevi, Jayakumar Thangavel, Raja Rajeswari Indiran, Srinivasan Gopalan

Fuel Cell Electric Vehicles (FCEVs) require more capable influence on adaptation schemes to ensure smooth operation and maximum energy utilization. Strong Maximum Power Point Tracking (MPPT) in the systems is challenging due to the fuel cell nonlinearity, dynamic loads, and fluctuating ambient conditions. Conventional MPPT methods are marred by slow convergence, local optimum trapping, and poor tracking of sudden transients. To eliminate these limitations, this manuscript presented a high-gain interleaved DC–DC converter (HGIDCDCC)-based optimum MPPT control method with the Starfish Optimization Algorithm (SFOA) and Putterfish Algorithm (PFA). The method benefits from the high voltage gain (VG) and ripple rejection of the interleaved converter, while SFOA–PFA hybrid optimization improves the MPPT displays in terms of higher convergence rate, global search ability, and steady-state stability. The designed converter structure and MPPT controller enhance the power conversion efficiency, voltage regulation, fuel cell temperature change response, and output power in all validated environments. In addition to FCEVs, the approach is also supportive of hybrid renewable power and storage systems, in which stable voltage, efficiency, and reliability are essential. The accuracy of the proposed approach is 99%.

燃料电池电动汽车(fcev)需要对适应方案施加更大的影响,以确保其平稳运行和最大限度地利用能源。由于燃料电池的非线性、动态负载和波动的环境条件,系统中的强最大功率点跟踪(MPPT)具有挑战性。传统的MPPT方法存在收敛速度慢、局部最优捕获和对突发瞬态跟踪差的缺点。为了消除这些限制,本文提出了一种基于海星优化算法(SFOA)和Putterfish算法(PFA)的高增益交错DC-DC转换器(HGIDCDCC)的最优MPPT控制方法。该方法受益于交错变换器的高电压增益和抑制纹波,而SFOA-PFA混合优化在更高的收敛速度、全局搜索能力和稳态稳定性方面改进了MPPT显示。设计的转换器结构和MPPT控制器提高了功率转换效率、电压调节、燃料电池温度变化响应以及在所有验证环境下的输出功率。除了fcev,该方法还支持混合可再生能源和存储系统,其中稳定的电压、效率和可靠性至关重要。该方法的准确率为99%。
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引用次数: 0
Diamond-Like-Carbon Coated Metallic Bipolar Plates for PEM Fuel Cells: An Assessment of Coating Thickness Effect 用于PEM燃料电池的类金刚石-碳涂层金属双极板:涂层厚度效应的评估
IF 3.1 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-12-01 DOI: 10.1002/fuce.70036
Pramoth Varsan Madhavan, Shams Anwar, Samaneh Shahgaldi, Xianguo Li

Metallic bipolar plates are key to low-cost compact stack design for proton exchange membrane (PEM) fuel cells, but suffer serious surface corrosion and require surface protective coatings such as diamond-like-carbon (DLC). In this study, the impact of DLC coating thickness on the corrosion characteristics of SS316L bipolar plates is investigated in an ex-situ environment simulating the operating environment in PEM fuel cells, and three coating thicknesses of 47, 100, and 197 nm are evaluated for their surface morphology, composition, corrosion resistance, wettability, and interfacial contact resistance. x-Ray photoelectron spectroscopy measurements reveal the sp2 (graphite-like) to sp3 (diamond-like) hybridization ratio, while scanning electron microscopy results show dense coating layer structures. Corrosion resistance is assessed using potentiostatic and potentiodynamic polarizations and electrochemical impedance spectroscopy (EIS) in a simulated fuel cell environment with 1 M H2SO4 at 80°C. It is found that all coated samples meet the US Department of Energy (DOE) targets for corrosion resistance, and the 100 nm thick DLC coating shows the best performance, with the lowest corrosion current density (0.110 µA/cm2), highest corrosion potential (17.31 mV), and highest resistance to charge transfer (5.36·106 Ω cm2); and maintain hydrophobicity (contact angle of 92° and surface free energy of 17.00 mJ/m2) after 5 h of potentiostatic polarization, suggesting excellent potential for water management and corrosion resistance. Further, these coated samples meet the DOE targets for interfacial contact resistance of < 10 mΩ cm2. Therefore, the 100 nm thick DLC coating demonstrates superior anticorrosion performance required for PEM fuel cell applications.

金属双极板是质子交换膜(PEM)燃料电池低成本紧凑堆设计的关键,但其表面腐蚀严重,需要类金刚石(DLC)等表面保护涂层。在模拟PEM燃料电池工作环境的非原位环境中,研究了DLC涂层厚度对SS316L双极板腐蚀特性的影响,并评估了47、100和197 nm三种涂层厚度对其表面形貌、组成、耐腐蚀性、润湿性和界面接触电阻的影响。x射线光电子能谱测量显示sp2(类石墨)与sp3(类金刚石)杂化比,扫描电镜结果显示致密的涂层层结构。在模拟燃料电池环境中,采用恒电位和动电位极化以及电化学阻抗谱(EIS),在80°C下使用1 M H2SO4进行耐蚀性评估。结果表明,涂层样品均满足美国能源部(DOE)的耐腐蚀指标,其中100 nm厚的DLC涂层性能最佳,腐蚀电流密度最低(0.110µA/cm2),腐蚀电位最高(17.31 mV),电荷转移电阻最高(5.36·106 Ω cm2);并在静电位极化5 h后保持疏水性(接触角为92°,表面自由能为17.00 mJ/m2),具有良好的水管理和耐腐蚀潜力。此外,这些涂层样品满足DOE目标的界面接触电阻为<; 10 mΩ cm2。因此,100纳米厚的DLC涂层显示出PEM燃料电池应用所需的卓越防腐性能。
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引用次数: 0
Multi-Objective Optimization of Operating Parameters of Proton Exchange Membrane Fuel Cells by Coupling Surrogate Model and Intelligent Algorithm 基于耦合代理模型和智能算法的质子交换膜燃料电池运行参数多目标优化
IF 3.1 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-11-30 DOI: 10.1002/fuce.70033
Caizhi Zhang, Yifei Shao, Shengfu Deng, Jinrui Chen, Chuanyu Sun, Sergey A. Grigoriev, Junjie Ge, Gang Lei

Operating parameters of Proton Exchange Membrane Fuel Cells (PEMFCs) are important for its output performance and real time control. However, in existing studies, the methods for optimizing its operating parameters either focus on only one aspect, or the multi-objective optimization process, and is excessively time-consuming. This study proposes a novel hybrid framework that couples a deep neural network surrogate model with the Non-dominated Sorting Genetic Algorithm II (NSGA-II) for multi-objective optimization of fuel cell operating parameters. Seven key operating parameters—including voltage, temperature, pressure, stoichiometric ratios, and humidity—are selected as decision variables, while power density, system efficiency, and oxygen distribution uniformity serve as optimization objectives. The surrogate model is constructed using an Adam-optimized backpropagation neural network (Adam-BP), trained on a dataset generated through orthogonal design and numerical simulations. The model achieves high accuracy in performance prediction and is integrated with NSGA-II to rapidly generate Pareto-optimal solutions. The optimal operating parameters are further selected using the CRITIC method, which enables adaptive weighting based on data variability and correlation. Results show that the proposed method improves power density by 27%, system efficiency by 9.7%, and oxygen distribution uniformity by 6.6% compared to baseline conditions. This approach offers a fast, accurate, and systematic tool for PEMFC performance optimization, with strong potential for engineering application.

质子交换膜燃料电池(pemfc)的运行参数对其输出性能和实时控制至关重要。然而,在现有的研究中,其运行参数的优化方法要么集中在一个方面,要么是一个多目标的优化过程,并且耗时过长。本研究提出了一种新的混合框架,将深度神经网络代理模型与非支配排序遗传算法II (NSGA-II)相结合,用于燃料电池运行参数的多目标优化。七个关键操作参数——包括电压、温度、压力、化学计量比和湿度——被选为决策变量,而功率密度、系统效率和氧气分布均匀性作为优化目标。该代理模型使用adam优化的反向传播神经网络(Adam-BP)构建,并在正交设计和数值模拟生成的数据集上进行训练。该模型具有较高的性能预测精度,并与NSGA-II集成,可快速生成pareto最优解。使用CRITIC方法进一步选择最佳操作参数,该方法可以基于数据可变性和相关性进行自适应加权。结果表明,与基准条件相比,该方法提高了功率密度27%,系统效率提高9.7%,氧气分布均匀性提高6.6%。该方法为PEMFC性能优化提供了一种快速、准确、系统的工具,具有很强的工程应用潜力。
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引用次数: 0
Membrane-Less Microbial Fuel Cells for Energy Production—A Comprehensive Review 用于能源生产的无膜微生物燃料电池综述
IF 3.1 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-11-29 DOI: 10.1002/fuce.70032
Aswathi Mahesh, Ganesh Mahidhara

Microbial fuel cells (MFC) are gaining popularity as energy solutions because they harness microbial metabolism to transform organic materials directly into electricity. Membrane-less MFC serve as an alternative to traditional membrane-based systems, providing benefits like reduced cost, simplified design, minimized fouling, and improved scalability. However, the lack of a membrane in membrane-less MFC could lead to short-circuiting of electrochemical reactions along with instability of microbial community over time, resulting in instability, low power production, and decreased efficiency. To improve their performance and long-term stability, reactor designs and microbial-electrode interactions must be improved. This review article delivers a thorough analysis of the latest developments, challenges, and applications of electrogenic bacteria within anodic biofilms for energy generation in MFC. It highlights the potential of membrane-less MFC in advancing this technology by exploring key aspects such as design principles, strategies for improving performance, viable organic substrates, and future outlooks.

微生物燃料电池(MFC)作为能源解决方案越来越受欢迎,因为它们利用微生物代谢将有机材料直接转化为电能。无膜MFC是传统膜系统的替代方案,具有降低成本、简化设计、最小化污垢和提高可扩展性等优点。然而,在无膜MFC中缺乏膜可能导致电化学反应短路以及微生物群落随着时间的推移而不稳定,从而导致不稳定,低功率产生和效率降低。为了提高它们的性能和长期稳定性,必须改进反应器设计和微生物电极相互作用。本文综述了电致细菌在阳极生物膜中用于MFC发电的最新进展、挑战和应用。它通过探索诸如设计原则、提高性能的策略、可行的有机底物和未来前景等关键方面,突出了无膜MFC在推进该技术方面的潜力。
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引用次数: 0
A Hybrid MPPT Algorithm for Fuel Cell Stack Based on Fuzzy Rules and Genetic Particle Swarm Optimization 一种基于模糊规则和遗传粒子群优化的燃料电池堆混合MPPT算法
IF 3.1 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-11-29 DOI: 10.1002/fuce.70035
Qiyuan Tong, Tao Wang

Proton exchange membrane fuel cells (PEMFCs) serve as crucial components in renewable energy systems, owing to their exceptional efficiency and minimal emissions. This research presents a fused maximum power point tracking (MPPT) approach for a 6 kW PEMFC system, integrating fuzzy logic control (FLC) with genetic algorithm-augmented particle swarm optimization (GA-PSO). A rigorous mathematical model of the PEMFC is formulated and experimentally corroborated. A fuzzy logic controller addresses system nonlinearity, while the GA-PSO algorithm dynamically optimizes the fuzzy rule base to adapt to varying operating conditions. Simulations compare the Mamdani controller and the GA-PSO hybrid controller interfaced with a DC–DC boost converter (45–85.34 V). Results demonstrate that the GA-PSO controller achieves 99.7% tracking efficiency (vs. 96.33% for Mamdani) with shorter rise time (5.15 vs. 5.03 ms), lower overshoot (9.17% vs. 10.34%), and enhanced robustness. The hybrid controller effectively tracks maximum power under dynamic loads and environmental changes, proving its superiority in steady-state accuracy and adaptability. This work provides a practical solution for optimizing PEMFC energy output.

质子交换膜燃料电池(pemfc)因其卓越的效率和极低的排放而成为可再生能源系统的重要组成部分。提出了一种融合模糊逻辑控制(FLC)和遗传算法增强粒子群优化(GA-PSO)的6kw PEMFC系统最大功率点跟踪(MPPT)方法。建立了PEMFC的数学模型,并进行了实验验证。模糊控制器解决了系统的非线性问题,GA-PSO算法动态优化模糊规则库以适应不同的运行条件。仿真比较了Mamdani控制器和GA-PSO混合控制器与DC-DC升压转换器(45-85.34 V)的接口。结果表明,GA-PSO控制器具有较短的上升时间(5.15 ms vs. 5.03 ms)、较低的超调量(9.17% vs. 10.34%)和增强的鲁棒性,达到99.7%的跟踪效率(Mamdani为96.33%)。混合控制器在动态负载和环境变化下能有效跟踪最大功率,证明了其稳态精度和自适应性的优越性。这项工作为优化PEMFC能量输出提供了实用的解决方案。
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引用次数: 0
Microporous Layer Design for Active DMFC Using CNF-TiO2 Integration to Mitigate Methanol Crossover and Improve Power Density 利用CNF-TiO2集成有源DMFC的微孔层设计以减轻甲醇交叉并提高功率密度
IF 3.1 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-11-29 DOI: 10.1002/fuce.70031
Muhammad Syafiq Alias, Siti Kartom Kamarudin, Ang Wei Lun, Nabila A. Karim

Direct Methanol Fuel Cells (DMFCs) are attractive for portable applications but face persistent challenges, including methanol crossover, poor catalyst layer adhesion, and inefficient mass transport associated with conventional microporous layers (MPLs). These deficiencies limit catalyst utilization and water management, resulting in reduced power output and stability. To address these challenges, this study developed a titanium dioxide–carbon nanofiber (TiO2–CNF) hybrid MPL via slurry seeping fabrication. The composite structure leverages CNF's high conductivity and TiO2’s catalytic stability to achieve optimized porosity (69.85%) and balanced micro/mesopore distribution. Electrochemical testing revealed a 17.58% enhancement in peak power density at 4 M methanol concentration compared with CNF-based MPLs, alongside a reduction in crossover-induced losses from 71.9% to 39.46%. The CNF–TiO2 interface promoted efficient charge transfer, maintained stable operation, and improved reactant/product transport, thereby enhancing overall DMFC efficiency. These results demonstrate that the TiO2–CNF hybrid MPL provides a robust and scalable solution to overcome mass transport and stability limitations, offering a significant advancement toward practical DMFC systems for compact and portable power devices.

直接甲醇燃料电池(dmfc)在便携式应用中具有吸引力,但面临着持续的挑战,包括甲醇交叉,催化剂层粘附性差,以及与传统微孔层(MPLs)相关的低质量传输。这些缺陷限制了催化剂的利用和水的管理,导致功率输出和稳定性降低。为了解决这些挑战,本研究通过浆液渗透制备方法开发了二氧化钛-碳纳米纤维(TiO2-CNF)混合MPL。复合结构利用CNF的高导电性和TiO2的催化稳定性,实现了优化的孔隙率(69.85%)和平衡的微孔/中孔分布。电化学测试显示,与基于cnf的MPLs相比,4 M甲醇浓度下的峰值功率密度提高了17.58%,同时交叉引起的损耗从71.9%降低到39.46%。CNF-TiO2界面促进了高效的电荷转移,保持了稳定的运行,改善了反应物/产物的传输,从而提高了DMFC的整体效率。这些结果表明,TiO2-CNF混合MPL提供了一种强大且可扩展的解决方案,可以克服质量传输和稳定性限制,为紧凑型和便携式电源设备的实际DMFC系统提供了重大进展。
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引用次数: 0
Degradation Prediction of Proton Exchange Membrane Fuel Cell Under Dynamic Loading Conditions Using Algorithm-Optimized Long Short-Term Memory Models 基于算法优化长短期记忆模型的质子交换膜燃料电池动态加载退化预测
IF 3.1 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-10-30 DOI: 10.1002/fuce.70030
Nguyen Thanh Ta, Doan Quoc Huy, Tran Ngoc Tien Phat, Nguyen Nhat Kim Ngan, Nguyen Manh Tuan, Nguyen Huynh My Tue, Vo Thi Kim Yen, Doan Thi Kim Ngan, Tran Duy Tap

Long short-term memory (LSTM) and bidirectional long short-term memory (Bi-LSTM) neural networks are utilized to predict the performance degradation of proton exchange membrane fuel cells using a dataset of 550 h obtained from the Federation for Fuel Cell Research (FCLAB). The model performance is optimized using Bayesian optimization long short-term memory (BO-LSTM), ant colony optimization long short-term memory (ACO-LSTM), Bayesian optimization bidirectional long short-term memory (BO-Bi-LSTM), and ant colony optimization bidirectional long short-term memory (ACO-Bi-LSTM). For each above model, how different parameters such as the number of hidden nodes, dropout rate, learning rate, and number of hidden layers affect the prediction results are carefully examined. The results show that the mean absolute percent error (MAPE) of BO-LSTM, ACO-LSTM, BO-Bi-LSTM, and ACO-Bi-LSTM models with a training rate of 80% are approximately 0.000230, 0.000394, 0.000218, and 0.000181, respectively. Note that the obtained MAPE values are improved significantly as compared with those (MAPE = 0.0518–0.0097) of previous reports, leading to the potential application of proposed models for similar fuel cell systems.

利用燃料电池研究联合会(FCLAB)提供的550小时数据集,利用长短期记忆(LSTM)和双向长短期记忆(Bi-LSTM)神经网络预测质子交换膜燃料电池的性能退化。采用贝叶斯优化长短期记忆(BO-LSTM)、蚁群优化长短期记忆(ACO-LSTM)、贝叶斯优化双向长短期记忆(BO-Bi-LSTM)和蚁群优化双向长短期记忆(ACO-Bi-LSTM)对模型性能进行优化。对于上述每个模型,仔细检查了隐藏节点数、辍学率、学习率、隐藏层数等不同参数对预测结果的影响。结果表明,在训练率为80%的情况下,BO-LSTM、ACO-LSTM、BO-Bi-LSTM和ACO-Bi-LSTM模型的平均绝对百分误差(MAPE)分别约为0.000230、0.000394、0.000218和0.000181。值得注意的是,与之前报告的MAPE值(MAPE = 0.0518-0.0097)相比,得到的MAPE值有了显著提高,这使得所提出的模型有可能应用于类似的燃料电池系统。
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引用次数: 0
Influence of Sr Concentration and A-Site Deficiency on the (La1−ySry)xCr0.5Mn0.45Ni0.05O3−δ Solid Oxide Cell Electrode Properties Sr浓度和a位缺乏对(La1−ySry)xCr0.5Mn0.45Ni0.05O3−δ固体氧化物电池电极性能的影响
IF 3.1 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-10-26 DOI: 10.1002/fuce.70028
Indrek Kivi, Laur Kristjan Salvan, Ove Korjus, Jaan Aruväli, Priit Möller, Gunnar Nurk

In this study, the La/Sr ratio and A-site deficiency of (La1−ySry)xCr0.5Mn0.45Ni0.05O3−δ (LSCMN) were systematically varied to investigate the effect of these modifications on lattice parameters, surface composition, and initial electrochemical performance. Studied materials were thermally treated in oxidizing and reducing gas environments and thereafter analyzed using X-ray diffraction (XRD), time-of-flight secondary ion mass spectrometry (TOF-SIMS), and electrochemical analysis methods. X-ray analysis of samples heat-treated in air revealed that the La/Sr ratio influences the Mn3+/Mn4+ ratio in LSCMN material, but the influence of A-site deficiency is minor. After thermal treatment in a highly reducing environment, expansion of lattice parameters was observed, caused by the reduction of Ni2+ to Ni0 and partial reduction of Mn4+ to Mn3+ and simultaneous formation of oxide ion vacancies. The highest lattice changes were observed in the highest Sr concentration and at the 1%–3% A-site deficiency range.

The highest electrochemical activity was observed when the Sr content remained low (y = 0.2). The most stable systems had low A-site deficiency. The study reveals that chemical and structural characteristics of the electrode surface, particularly the segregation of LSCMN components, play an essential role in the electrochemical performance and stability.

在本研究中,系统地改变了(La1−ySry)xCr0.5Mn0.45Ni0.05O3−δ (LSCMN)的La/Sr比和a位缺位,研究了这些修饰对晶格参数、表面组成和初始电化学性能的影响。所研究的材料在氧化和还原性气体环境中进行热处理,然后使用x射线衍射(XRD)、飞行时间二次离子质谱(TOF-SIMS)和电化学分析方法进行分析。在空气中热处理样品的x射线分析表明,La/Sr比影响LSCMN材料中Mn3+/Mn4+的比例,但a位缺位的影响较小。在高还原环境下热处理后,观察到晶格参数的膨胀,这是由Ni2+还原为Ni0和Mn4+部分还原为Mn3+引起的,同时形成氧化离子空位。在最高锶浓度和1%-3% a位缺失范围内观察到最大的晶格变化。当Sr含量较低(y = 0.2)时,电化学活性最高。最稳定的系统具有低a位缺乏症。研究表明,电极表面的化学和结构特征,特别是LSCMN组分的偏析,对电化学性能和稳定性起着至关重要的作用。
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引用次数: 0
Enhanced Accuracy in PEM Fuel Cell Modeling Using Load-Dependent Semiempirical Approaches 使用负载相关的半经验方法提高PEM燃料电池建模的准确性
IF 3.1 4区 工程技术 Q3 ELECTROCHEMISTRY Pub Date : 2025-10-26 DOI: 10.1002/fuce.70029
Martin Ćalasan, Snežana Vujošević

Proton exchange membrane fuel cells (PEMFCs) play a central role in the transition to clean hydrogen-based energy systems. However, conventional models with fixed empirical parameters often fail to predict performance under variable operating conditions accurately. This paper introduces two novel PEMFC models with load-dependent formulations of the activation overpotential constant and its temperature coefficient, parameters shown to have the greatest sensitivity to load variation. Using the artificial hummingbird algorithm (AHA) for parameter optimization, the models were tested on four representative PEMFC configurations (Ballard-Mark-V 5 kW PEMFC, BCS 500 W, NedStack PS6 6 kW PEMFC, and Horizon 500 W). The results demonstrate a consistent reduction in prediction error compared with state-of-the-art models, with an improvement of up to 89.97% in RMSE for the Horizon cell. Sensitivity and robustness analyses further confirm stable performance under varying temperature and pressure conditions. These findings suggest that the proposed models offer a reliable and computationally efficient foundation for advanced simulation, control, and optimization of PEMFC systems in real-world applications.

质子交换膜燃料电池(pemfc)在向清洁氢基能源系统过渡的过程中发挥着核心作用。然而,传统的经验参数固定的模型往往不能准确地预测可变工况下的性能。本文介绍了两种新型的PEMFC模型,其激活过电位常数及其温度系数的表达式与负载有关,这两种参数对负载变化的敏感性最大。利用人工蜂鸟算法(AHA)进行参数优化,在四种典型PEMFC配置(Ballard-Mark-V 5kw PEMFC、BCS 500w、NedStack PS6 6kw PEMFC和Horizon 500w)上对模型进行了测试。结果表明,与最先进的模型相比,该模型的预测误差持续降低,Horizon单元的RMSE提高了89.97%。灵敏度和鲁棒性分析进一步证实了在不同温度和压力条件下的稳定性能。这些发现表明,所提出的模型为实际应用中PEMFC系统的高级仿真、控制和优化提供了可靠且计算效率高的基础。
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引用次数: 0
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Fuel Cells
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