Synthesis of magnetic activated carbon-supported cobalt(II) chloride derived from pecan shell (Aleurites moluccana) with co-precipitation method as the electrode in supercapacitors

Muhammadin Hamid , Susilawati , Suci Aisyah Amaturrahim , Ivi Briliansi Dalimunthe , Amru Daulay
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Abstract

The synthesis of materials on magnetic activated carbon is of concern, with a simple and environmentally friendly. The research used pecan shell (Aleurites moluccana) as a carbon source. The breakthrough made in this research is to make magnetic activated carbon electrodes in supercapacitors. Obtained on the XRD diffractograms show the graphite lattice, respectively. Also, a sharp, narrow peak is seen at 2θ = 26° in the carbon samples spectrum, showing a highly graphitized fraction. FESEM-EDX showed AC20/80 that the shape of the particles was like plates indicating that the particles had been formed. AC80/20 is the surface morphology in which particles with irregular shapes indicate that particles have been formed, where the shape of the particles is irregular. The composition between C and O is also balanced. AC80/20 has lower Co content than AC20/80, AC40/60, AC60/40, and AC50/50 and it appears that AC80/20 is better than the others. The magnitude of the coercivity states that AC20/80, AC80/20, AC40/60, AC60/40, and AC50/50 are strong magnets. The lower the value of the open circuit potential, it will show electrochemical stability. The Nyquist plots of magnetic activated carbon show a straight vertical indicating the process of charge transfer resistance at the low electrode. Obtained specific capacitance AC80/20 at 150F/g.

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用共沉淀法合成以山核桃壳为原料制备的磁性活性炭负载的氯化钴(II)
磁性活性炭材料的合成备受关注,具有简单环保的特点。该研究使用山核桃壳(Aleurites moluccana)作为碳源。本研究的突破是在超级电容器中制备磁性活性炭电极。所得的XRD衍射图上分别显示了石墨的晶格。碳样品的光谱在2θ = 26°处有一个尖峰,表明石墨化程度较高。FESEM-EDX显示AC20/80,颗粒的形状类似板,表明颗粒已经形成。AC80/20为表面形貌,其中形状不规则的颗粒表示已经形成颗粒,其中颗粒形状不规则。C和O的组成也是平衡的。AC80/20的Co含量低于AC20/80、AC40/60、AC60/40和AC50/50,其中AC80/20的Co含量较好。矫顽力的大小说明AC20/80、AC80/20、AC40/60、AC60/40、AC50/50为强磁体。开路电位值越低,则表现出电化学稳定性。磁性活性炭的奈奎斯特图呈直线垂直,表示低电极处电荷转移电阻的过程。在150F/g下得到比电容AC80/20。
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来源期刊
Materials Science for Energy Technologies
Materials Science for Energy Technologies Materials Science-Materials Science (miscellaneous)
CiteScore
16.50
自引率
0.00%
发文量
41
审稿时长
39 days
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