{"title":"Chemistry of gem-difluorovinyl sulfonates","authors":"Cai Zhang","doi":"10.2174/1570193x19666220929114415","DOIUrl":null,"url":null,"abstract":"\n\nAmong various emerging organofluorine molecules, gem-difluorovinyl sulfonates are attractive building blocks and less used in organic reactions. This review article is concerned with recent advances in the organic reactions using gem-difluorovinyl sulfonates in recent years. We discussed the reactions of gem-difluorovinyl sulfonates with aldehydes, amines, imines, amides, boronic acids, aryl halides, etc. or addition, reduction, substitution and intramolecular 1,3-sulfonyl migration of gem-difluorovinyl sulfonates in nine approaches. The synthetic strategies described in this review provided diversely substituted fluorinated molecules.\n","PeriodicalId":18632,"journal":{"name":"Mini-reviews in Organic Chemistry","volume":" ","pages":""},"PeriodicalIF":1.9000,"publicationDate":"2022-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Mini-reviews in Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.2174/1570193x19666220929114415","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
Among various emerging organofluorine molecules, gem-difluorovinyl sulfonates are attractive building blocks and less used in organic reactions. This review article is concerned with recent advances in the organic reactions using gem-difluorovinyl sulfonates in recent years. We discussed the reactions of gem-difluorovinyl sulfonates with aldehydes, amines, imines, amides, boronic acids, aryl halides, etc. or addition, reduction, substitution and intramolecular 1,3-sulfonyl migration of gem-difluorovinyl sulfonates in nine approaches. The synthetic strategies described in this review provided diversely substituted fluorinated molecules.
期刊介绍：
Mini-Reviews in Organic Chemistry is a peer reviewed journal which publishes original reviews on all areas of organic chemistry including organic synthesis, bioorganic and medicinal chemistry, natural product chemistry, molecular recognition, and physical organic chemistry. The emphasis will be on publishing quality papers very rapidly, without any charges.
The journal encourages submission of reviews on emerging fields of organic chemistry including:
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Carbohydrate Chemistry
Chemical Biology
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Computational Organic Chemistry
Development of Synthetic Methodologies
Functional Organic Materials
Heterocyclic Chemistry
Macromolecular Chemistry
Natural Products Isolation And Synthesis
New Synthetic Methodology
Organic Reactions
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Organometallic Chemistry
Theoretical Organic Chemistry
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Structural Investigations
Supramolecular Chemistry
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