Home-made cider brandy (Calvados): analysis of distillation fractions by gas chromatography-mass spectrometry method

IF 0.5 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Chemija Pub Date : 2021-11-09 DOI:10.6001/chemija.v32i3-4.4546
Indrė Vaičikauskytė, Vilius Poškus, V. Nekrošius, V. Vickackaite, A. Kareiva
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Abstract

In this study, the distillation fractions of cider brandy produced illegally in Lithuania using gas chromatographic-mass spectrometry method were investigated. The conditions of gas chromatography-mass spectrometry were firstly optimized. A qualitative analysis of three distillation fractions was performed and estimated. The first fraction (initial) of distillation products was collected for 0.5 h, the second one (intermediate) was collected for the next 1.5 h and the third (main) fraction for the next 5 h. A method of the quantitative analysis of different volatile analytes such as acetaldehyde, methanol, ethanol, 1-propanol, isobutanol, 1-butanol, isoamyl alcohol and benzyl alcohol in the distillation products was also developed. The concentration of ethanol decreased significantly in the main fraction in comparison with those of the initial and intermediate fractions. The concentration of 1-propanol, isobutanol, 1-butanol and isoamyl alcohol in the last fraction decreased drastically as well.
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自制苹果白兰地(Calvados):气相色谱-质谱联用分析
本研究采用气相色谱-质谱法对立陶宛非法生产的苹果白兰地的蒸馏馏分进行了研究。首先对气相色谱-质谱分析的条件进行了优化。对三种蒸馏馏分进行了定性分析并进行了估算。蒸馏产物的第一级分(初始)收集0.5小时,第二级分(中间体)收集1.5小时,第三级分(主要)收集5小时。不同挥发性分析物如乙醛、甲醇、乙醇、1-丙醇、异丁醇、1-丁醇、,还开发了蒸馏产物中的异戊醇和苯甲醇。与初始和中间馏分相比,主要馏分中的乙醇浓度显著降低。最后馏分中的1-丙醇、异丁醇、1-丁醇和异戊醇的浓度也急剧下降。
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来源期刊
Chemija
Chemija 化学-化学综合
CiteScore
1.30
自引率
16.70%
发文量
14
审稿时长
>12 weeks
期刊介绍: Chemija publishes original research articles and reviews from all branches of modern chemistry, including physical, inorganic, analytical, organic, polymer chemistry, electrochemistry, and multidisciplinary approaches.
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