A study on vermiculite-based salt mixture composite materials for low-grade thermochemical adsorption heat storage

Abstract

High-performance renewable energy technologies are desired to meet the enormous demand during the clean energy transition. Thermal energy storage can help balance the mismatch between renewable energy supplies and end-user's demands. Thermochemical adsorption heat storage (TAHS) has attracted widespread attention for its ability to efficiently utilise low-grade renewables and waste heat. Composite adsorbent materials have been gaining increased research interest, which combine hygroscopic salts and host matrix via impregnating salts in the matrix. This paper reviews recent progress in composite materials for TAHS and provides material characterisation analysis on different vermiculite-based composites. The composites use vermiculite as the host matrix with impregnation of different binary and ternary salt mixtures (i.e., MgSO₄–CaCl₂, MgCl₂–LiNO₃, MgSO₄–LiCl and MgSO₄–LiNO₃–MgCl₂). Vermiculite impregnated with a binary mixture of MgSO₄–CaCl₂ demonstrated a high energy storage density of 1213 kJ/kg, with fast desorption kinetics in the temperature range of low-grade heat. It shows good suitability for domestic TAHS applications, particularly for space heating, with stable cyclic performance over 20 charging-discharging cycles, maintaining approximately 91.3% of its initial energy storage density. The findings of this study contribute to the growing body of research on composite materials and demonstrate the potential of vermiculite-based composites impregnated with binary salt mixtures for low-grade TAHS.