Removal of As(III) from Water by Cellulase Templated TiO2: A Photocatalytic Oxidation Conjugated Adsorption Process

Liangzhong Jiang, L. Xie, Jiao He, Juanxue Kang, Wei Wang, Jiaqiang Wang
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Abstract

TiO2 photocatalyst was prepared using cellulase as a biotemplate through a hydrothermal process. The as-prepared catalyst was characterized based on physicochemical techniques and was used to remove As(III) from contaminated water. The cellulase templated TiO2 photocatalyst (TiO2-cellulase) had a large specific surface area, which reached 166.6 m2·g–1. It also had a strong oxidation ability and, thus, behaved well in both photocatalytic oxidation of As(III) and dark adsorption. The pH of the solution had a negligible effect on the removal rate. TiO2-cellulase had a higher photocatalytic removal rate of As(III) than commercial Degussa P25 TiO2.
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纤维素酶模板TiO2光催化氧化共轭吸附法去除水中砷(III
以纤维素酶为生物模板,通过水热法制备了TiO2光催化剂。用物理化学方法对制备的催化剂进行了表征,并将其用于去除污染水中的砷(III)。纤维素酶模板化的TiO2光催化剂(TiO2-纤维素酶)具有较大的比表面积,达到166.6 m2·g-1。它还具有很强的氧化能力,因此在光催化氧化As(III)和暗吸附中都表现良好。溶液的pH值对去除率的影响可以忽略不计。TiO2-纤维素酶对As(III)的光催化去除率高于德固赛P25 TiO2。
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