Applications of Polymethylhydrosiloxane (PMHS) in Organic Synthesis-Covering up to March 2022

IF 1.9 4区 化学 Q2 CHEMISTRY, ORGANIC Mini-reviews in Organic Chemistry Pub Date : 2022-10-21 DOI:10.2174/1570193x20666221021104906
Dr. Ravi Varala, M. M. Alam, Vittal Seema, Narsimhaswamy Dubasi, Mohan Kurra
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Abstract

Based on the type of metal or non-metal catalyst used, the authors of this paper have clearly highlighted the different applications of air stable, commercially viable, and environmentally friendly polymethylhydrosiloxane (PMHS) in organic synthesis or other allied reactions. The importance of PMHS was emphasised for the particular organic transformation's success. In addition to its well-known use as a reducing agent, it has also been demonstrated in a variety of other applications, including ring cleavage, the cotton industry, functional material for microfluidic chips, and the dehydroaromatization of bio-oils. The article tries to compile the most noteworthy cases of highly successful PMHS catalysis over the past two decades or so.
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截至2022年3月,聚甲基硅氧烷在有机合成中的应用
基于所用金属或非金属催化剂的类型,本文作者明确强调了空气稳定、商业可行和环境友好的聚甲基硅氧烷(PMHS)在有机合成或其他相关反应中的不同应用。强调了PMHS对于特定有机转化成功的重要性。除了作为还原剂的众所周知的用途外,它还被证明在各种其他应用中,包括环切割、棉花工业、微流体芯片的功能材料和生物油的脱氢芳构化。本文试图汇编过去二十年左右高度成功的PMHS催化的最值得注意的案例。
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来源期刊
Mini-reviews in Organic Chemistry
Mini-reviews in Organic Chemistry 化学-有机化学
CiteScore
4.50
自引率
4.30%
发文量
116
审稿时长
>12 weeks
期刊介绍: Mini-Reviews in Organic Chemistry is a peer reviewed journal which publishes original reviews on all areas of organic chemistry including organic synthesis, bioorganic and medicinal chemistry, natural product chemistry, molecular recognition, and physical organic chemistry. The emphasis will be on publishing quality papers very rapidly, without any charges. The journal encourages submission of reviews on emerging fields of organic chemistry including: Bioorganic Chemistry Carbohydrate Chemistry Chemical Biology Chemical Process Research Computational Organic Chemistry Development of Synthetic Methodologies Functional Organic Materials Heterocyclic Chemistry Macromolecular Chemistry Natural Products Isolation And Synthesis New Synthetic Methodology Organic Reactions Organocatalysis Organometallic Chemistry Theoretical Organic Chemistry Polymer Chemistry Stereochemistry Structural Investigations Supramolecular Chemistry
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