Heat treatment effect on the distribution of organic clay in polymer nanocomposites

Jie Tian, Shenzhen City China Shenzhen Power Supply Co. Ltd., Yuming Zhao, Qing Ding, J. Ai, Li Shouding, Qi Cheng
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Abstract

In this paper, the effects of heat treatment temperature on the degree of exfoliation of organic clay under different compatibilizers were tested by using organic clay 93A, high density polyethylene (HDPE) and compatibilizer (PE-g-MA), polyethylene maleic anhydride copolymer (PEMA), maleic anhydride and polyethylene blend (MA/PE). The proportion of organic clay is 5 wt%, HDPE is 90 wt% and compatibilizer is 5 wt%. Temperature ranged from 210oC to 250oC, the position of [001] peak in the sample was determined, FESEM, TGA, FTIR and XRD was used to analyze the influence of temperature on the distribution behavior of clay in polymer system. The results are very significant for the industrial production of clay composite materials.
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热处理对有机粘土在聚合物纳米复合材料中分布的影响
以有机粘土93A、高密度聚乙烯(HDPE)和相容剂(PE-g-MA)、聚乙烯-马来酸酐共聚物(PEMA)、马来酸酐和聚乙烯共混物(MA/PE)为试材,研究了热处理温度对不同相容剂作用下有机粘土剥离度的影响。有机粘土的比例为5wt%,HDPE为90wt%,相容剂为5wt%。温度范围为210℃至250℃,测定了[001]峰在样品中的位置,利用FESEM、TGA、FTIR和XRD分析了温度对粘土在聚合物体系中分布行为的影响。研究结果对粘土复合材料的工业化生产具有重要意义。
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