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Revolutionizing energy storage: Overcoming challenges and unleashing the potential of next generation Lithium-ion battery technology 储能革命:克服挑战,释放下一代锂离子电池技术的潜力
Pub Date : 2023-07-04 DOI: 10.25082/mer.2023.01.003
Md. Dipu Ahmed, K. Maraz
Lithium-ion (Li-ion) batteries have become the leading energy storage technology, powering a wide range of applications in today's electrified world. This comprehensive review paper delves into the current challenges and innovative solutions driving the supercharged future of lithium-ion batteries. It scrutinizes the limitations of energy density in existing batteries, exploring advanced electrode materials and designs that promise higher capacity. Safety concerns take center stage, with a focus on cutting-edge thermal management systems and materials. The imperative of sustainable sourcing is addressed, highlighting alternative materials and recycling strategies for a greener supply chain. Transformative breakthroughs, such as solid-state electrolytes and emerging battery chemistries, offer glimpses of the future. The paper also examines the applications and market perspectives of lithium-ion batteries in electric vehicles, portable electronics, and renewable energy storage. It concludes by emphasizing the transformative potential of lithium-ion batteries in accelerating the energy revolution and paving the way for a sustainable energy future.
锂离子(Li-ion)电池已成为领先的储能技术,在当今电气化世界中有着广泛的应用。这篇全面的综述论文深入探讨了当前的挑战和推动锂离子电池未来增压的创新解决方案。它仔细研究了现有电池能量密度的局限性,探索了有望提高容量的先进电极材料和设计。安全问题是中心舞台,重点是尖端的热管理系统和材料。解决了可持续采购的必要性,强调了绿色供应链的替代材料和回收战略。变革性的突破,如固态电解质和新兴的电池化学,提供了未来的一瞥。本文还探讨了锂离子电池在电动汽车、便携式电子产品和可再生能源存储方面的应用和市场前景。报告最后强调了锂离子电池在加速能源革命和为可持续能源未来铺平道路方面的变革潜力。
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引用次数: 0
Load-induced local phase transformation and modulus of shape memory alloys under spherical indentation by finite element method 球形压痕下形状记忆合金载荷诱导局部相变及模量的有限元分析
Pub Date : 2023-06-14 DOI: 10.25082/mer.2023.01.002
S. Saghaian, Y. Lu, S. Saghaian, H. Karaca
Shape memory alloys are a unique class of materials that are capable of large reversible deformations under external stimuli such as stress or temperature. The present study examines the phase transformations and mechanical responses of NiTi and NiTiHf shape memory alloys under the loading of a spherical indenter by using a finite element model. It is found that the indentation unloading curves exhibit distinct changes in slopes due to the reversible phase transformations in the SMAs. The normalized contact stiffness (F/S2) of the SMAs varies with the indentation load (depth) as opposed to being constant for conventional single-phase materials. The load-induced phase transformation that occurred under the spherical indenter was simulated numerically. It is observed that the phase transformation phenomenon in the SMA induced by an indentation load is distinctly different from that induced by a uniaxial load. A pointed indenter produces a localized deformation, resulting in a stress (load) gradient in the specimen. As a result, the transformation of phases in SMAs induced by an indenter can only be partially completed. The overall modulus of the SMAs varies continuously with the indentation load (depth) as the average volumetric fraction of the martensite phase varies. For NiTi (Ea > Em), the modulus decreases with the depth, while for NiTiHf (Ea < Em), the modulus increases with the depth. The predicted young modules during indentation modeling agree well with experimental results. Finally, the phase transformation of the SMAs under the indenter is not affected by the post-yield behavior of the materials.
形状记忆合金是一类独特的材料,能够在应力或温度等外部刺激下发生大的可逆变形。本文采用有限元模型研究了球形压头载荷下NiTi和NiTiHf形状记忆合金的相变和力学响应。结果表明,由于sma的可逆相变,压痕卸载曲线的斜率发生了明显的变化。sma的归一化接触刚度(F/S2)随压痕载荷(深度)的变化而变化,而传统单相材料的归一化接触刚度是恒定的。数值模拟了球形压头下载荷诱导的相变过程。观察到压痕载荷诱导的SMA相变现象与单轴载荷诱导的相变现象明显不同。尖压头产生局部变形,导致试样中的应力(载荷)梯度。因此,由压头诱导的sma中相的转变只能部分完成。sma的总模量随压痕载荷(深度)和马氏体相平均体积分数的变化而连续变化。对于NiTi (Ea < Em),模量随深度的增加而减小,而对于NiTiHf (Ea < Em),模量随深度的增加而增大。压痕模型预测的年轻模量与实验结果吻合较好。最后,压头下sma的相变不受材料屈服后行为的影响。
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引用次数: 0
Polymer electrolyte design strategies for high-performance and safe lithium-ion batteries: Recent developments and future prospects 高性能安全锂离子电池的聚合物电解质设计策略:最新进展和未来展望
Pub Date : 2023-05-19 DOI: 10.25082/mer.2023.01.001
Dipu Ahmed, K. Maraz
Although lithium-ion batteries have gained widespread use in high-performance and mobile industries, concerns about their safety due to the low boiling point of their organic liquid electrolyte have posed challenges to their further development. In response, solid polymer electrolytes have emerged as a promising alternative, characterized by low flammability, flexibility, and high safety relative to liquid electrolytes. However, commercialization has been hindered by limitations in Li-ion conductivity and mechanical properties. Recent research efforts have focused on addressing these limitations to improve the performance and safety of polymer-based Li-ion batteries. This review discusses the utilization of polymer materials to enhance battery safety and overcome previous challenges, with a particular emphasis on the design of robust artificial interfaces to increase battery stability. Furthermore, we discuss the prospects for the future of polymer-based battery industries.
尽管锂离子电池在高性能和移动行业中得到了广泛应用,但由于其有机液体电解质的低沸点,人们对其安全性的担忧对其进一步发展构成了挑战。作为回应,固体聚合物电解质已成为一种很有前途的替代品,其特点是相对于液体电解质具有低易燃性、灵活性和高安全性。然而,由于锂离子导电性和机械性能的限制,商业化受到阻碍。最近的研究工作集中在解决这些限制,以提高聚合物基锂离子电池的性能和安全性。这篇综述讨论了利用聚合物材料提高电池安全性和克服以前的挑战,特别强调了设计坚固的人工界面以提高电池稳定性。此外,我们还讨论了聚合物电池行业的未来前景。
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引用次数: 1
Relationship between applied load and clearance in suture knots 外加载荷与缝线结间隙的关系
Pub Date : 2022-01-01 DOI: 10.25082/mer.2022.01.002
Amena S. Shermadou, S. Lindheim, J. Yaklic, T. Goswami
Ethicon Coated Vicryl absorbable sutures of different diameters were studied in order to determine if a relationship exists between the load and measured clearance. A prototype was designed to simulate knot location. Tensile tests were conducted on the suture knots followed by clearance measurements after each load level was applied. From the results it was concluded that the measured clearance was directly proportional to the amount of load applied to the suture knot. Also, based on the diameter of the suture, the smaller the diameter, the lower was the total displacement of the knot or the clearance.
为了确定负载与测量间隙之间是否存在关系,研究了不同直径的Ethicon涂层Vicryl可吸收缝合线。设计了一个原型来模拟结的位置。对缝合节进行拉伸试验,然后在施加每个负载水平后测量间隙。结果表明,测得的间隙与施加在缝线结上的载荷成正比。此外,根据缝线的直径,直径越小,结的总位移或间隙越小。
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引用次数: 0
In-vivo damage development in Vena Cava Filter: Study of a retrieved device 腔静脉过滤器的体内损伤发展:一种回收装置的研究
Pub Date : 2022-01-01 DOI: 10.25082/mer.2022.01.001
Anne Marie Lutz, T. Goswami
This article was prepared from a project assigned in a graduate class, BME 7371, Failure Assessment of Medical Devices, taught at Wright State University by the senior author. The device was donated for the study which was successfully retrieved after 93 days in-vivo. Even-though the mechanical integrity of the device held in-tact, the microscopic observations revealed that the damage via corrosion and scratching took place on the surface of the device. The image reconstructed in 3D using image-J software to determine device roughness and depth-of-pits. Results presented in this paper show that damage starts developing in these devices after the implantation that resulted in premature failure in many cases as reported in the media and literature.
这篇文章是根据研究生班BME 7371,医疗器械失效评估的一个项目编写的,该课程由资深作者在赖特州立大学授课。该装置被捐赠用于该研究,并在体内使用93天后成功回收。尽管设备的机械完整性完好无损,但显微镜观察显示,设备表面发生了腐蚀和刮擦造成的损伤。利用image- j软件对图像进行三维重建,确定器件粗糙度和凹坑深度。本文的结果表明,在植入这些装置后,损伤开始发展,导致媒体和文献中报道的许多情况下过早失效。
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引用次数: 0
Degradation mechanisms of zinc-air batteries used in hearing aid 助听器用锌空气电池的降解机理
Pub Date : 2022-01-01 DOI: 10.25082/mer.2022.01.004
Kelly Hunt, Mallory Bates, Gerald Klint Simon, Tarun Goswami
Hearing aid devices are powered by the oxidation of oxygen and zinc that occurs within zinc-air batteries. Zinc-air batteries have an average discharge time of 7 days. Therefore, hearing-aid devices need frequent battery replacement. In this paper, degradation mechanisms of zinc-air batteries investigated where a competition mechanism between zinc passivation and dendritic formation dictates the battery life. This research included exposure time from none to 9 days and to document dendritic growth with time. Scanning electron microscope images were taken to quantify the damage growth as well energy dispersive X-ray tests were conducted to comment on the composition changes. The results confirmed an increase in oxygen in exposed batteries from unexposed. These results matched findings from past literature. Exposure time was investigated to optimize battery lifespan. In conclusion, life of zinc-air batteries depends on the competition mechanism of zinc passivation and dendritic formation caused by oxidation and our investigation shows that this occurs within the first 7 days.
助听器是通过锌空气电池中氧气和锌的氧化来提供动力的。锌空气电池的平均放电时间为7天。因此,助听器需要经常更换电池。本文研究了锌-空气电池的降解机制,其中锌钝化和枝晶形成之间的竞争机制决定了电池寿命。这项研究包括从零到9天的暴露时间,并记录树突随时间的生长。通过扫描电镜图像量化损伤的生长情况,并通过x射线能量色散测试对成分变化进行评价。结果证实,暴露的电池中的氧气含量比未暴露的电池有所增加。这些结果与过去文献的发现相吻合。研究了曝光时间以优化电池寿命。总之,锌-空气电池的寿命取决于锌钝化和氧化引起的枝晶形成的竞争机制,我们的研究表明,这种竞争机制发生在电池的前7天。
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引用次数: 0
Synthesis of an eco-friendly composite of palygorskite-gypsum associated ore using corn starch and waste biomass 利用玉米淀粉和废生物质合成生态友好型坡缕石-石膏伴生矿复合材料
Pub Date : 2022-01-01 DOI: 10.25082/mer.2021.01.006
Haifeng Tian, Peng Gao, Hai-Xin Tian, F. Zha, Zengjun Wang, Xiaojun Guo, Xiaohua Tang, Yue Chang
Composite materials were prepared with palygorskite-gypsum associated ore, modified corn starch and corn stalk as raw materials, glycerin as plasticizer, ammonium persulfate as initiator, KH-560 as organosilane coupling agent and linseed gum as adhesion promoter. Tensile strength, flexural resistance and compressive strength were used as the evaluation criteria to investigate the optimal ratio of composite material. The effect of the content of palygorskite-gypsum associated ore and glycerol, the ratio of modified starch to corn stalk as well as the ratio of initiator to coupling agent on the mechanical properties was investigated. Composite materials were characterized by means of SEM, FT-IR, XRD and TG/DTG. The impact on the environment of composite material was evaluated via measuring the degradation and bacteriostatic properties. The degradation rate of the composite reached 52.7% when the degradation time was 42 d and the composite had a good antibacterial property.
以坡缕石-石膏伴生矿、改性玉米淀粉和玉米秸秆为原料,甘油为增塑剂,过硫酸铵为引发剂,KH-560为有机硅烷偶联剂,亚麻籽胶为粘结促进剂制备复合材料。以抗拉强度、抗折强度和抗压强度为评价标准,探讨复合材料的最佳配比。考察了坡缕石-石膏伴生矿和甘油的含量、改性淀粉与玉米秸秆的比例以及引发剂与偶联剂的比例对其力学性能的影响。采用SEM、FT-IR、XRD和TG/DTG对复合材料进行了表征。通过测定复合材料的降解性能和抑菌性能,评价复合材料对环境的影响。当降解时间为42 d时,复合材料的降解率达到52.7%,具有良好的抗菌性能。
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引用次数: 0
Residual properties of silicone (MED-4719) lead with leads from retrieved devices 有机硅(MED-4719)引线的残留特性与从回收的设备引线
Pub Date : 2022-01-01 DOI: 10.25082/mer.2022.01.005
A. Salih, Tarun Goswami
Leads are designed for in vivo applications, however, for a definite period of time. In-vivo environment affects the mechanical behavior of implantable devices, therefore, there is a need to evaluate the residual properties of implantable leads used with pacemakers, defibrillator and neuro-stimulators. Silicone (MED-4719) lead is widely used in cardiac implantable electronic devices made by different manufacturers. . We collected 150 devices (with or without leads) from Anatomical Gift Program of the Wright State University. The objective of this study was to investigate the residual properties of Silicone (MED-4719) lead with different in vivo exposure time and compare the properties of a new, unused lead supplied by Medtronic for the purposes of this research. The tensile test was performed by applying specific load on the samples, percentage elongation at 5N and the corresponding displacement measured. Load to failure, percentage elongation, ultimate tensile strength, and modulus of elasticity were determined for each lead. Methods to collect and compile data were standardized, and statistical models were used to assess the sensitivity of measured parameters with in vivo performance. Load to failure, elongation to failure, ultimate tensile strength, and percentage elongation at 5N showed a significant decrease after 94 months (P = 0.0063), 8 months (P = 0.0136), 94 months (P = 0.0244) and 71 months (P-value = 0.0326) after implantation, respectively. On the other hand, modulus of elasticity was found proportional to the number of months device was exposed and showed significant increase after 71 months (P = 0.0446) of in-vivo environment.
然而,引线是为体内应用而设计的,有一定的时间。体内环境影响植入式装置的机械行为,因此,有必要评估与起搏器、除颤器和神经刺激器一起使用的植入式导联的残留特性。硅胶(MED-4719)引线广泛应用于不同厂家生产的心脏植入式电子设备。我们从赖特州立大学的解剖捐赠项目中收集了150个设备(带或不带导线)。本研究的目的是研究不同体内暴露时间下有机硅(MED-4719)铅的残留特性,并比较美敦力公司为本研究提供的一种新的未使用铅的特性。拉伸试验是通过对试样施加比载荷,在5N时测量伸长率和相应的位移来进行的。对每根引线进行了失效载荷、伸长率、极限抗拉强度和弹性模量的测定。标准化数据收集和整理方法,采用统计模型评价所测参数与体内性能的敏感性。植入后94个月(P = 0.0063)、8个月(P = 0.0136)、94个月(P = 0.0244)和71个月(P值= 0.0326),载荷失效率、断裂伸长率、极限抗拉强度和5N伸长率均显著降低。另一方面,弹性模量与装置暴露的月数成正比,在体内环境71个月后,弹性模量显著增加(P = 0.0446)。
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引用次数: 1
Comparison of aero engine component lifing methods 航空发动机部件吊装方法比较
Pub Date : 2022-01-01 DOI: 10.25082/mer.2022.01.003
Ashley Whitney-Rawls, Paul Copp, Jace Carter, Tarun Goswami
Failure of critical engine components such as compressor, fan, and turbine disks during flight can cause the loss of the engine, aircraft, or even life. To reduce the risk of this failure during flight, different methodologies and tools have been developed to determine the safe operating life of these critical disk components. The two most widely used lifing methods, safe-life and damage tolerance, are inherently conservative, retiring all components when a predetermined operating limit is reached. Both methods retire components with theoretical useful life remaining. Additional lifing methods can be used to reduce this conservatism and extend the life of these components. Retirement for cause, developed within the United States Air Force is a lifing method that can extend the life of components by retiring a component only when there is cause to do so. Military and industry standards on lifing methodologies were reviewed. Both deterministic and probabilistic approaches to disk lifing methods are discussed as well as current tools. This paper provides a comparison of the methodologies and tools currently being used today by both the government and industry.
在飞行过程中,压气机、风扇、涡轮盘等关键发动机部件的故障可能会导致发动机、飞机甚至寿命的损失。为了降低飞行过程中这种故障的风险,已经开发了不同的方法和工具来确定这些关键磁盘组件的安全运行寿命。两种最广泛使用的寿命方法,安全寿命和损伤容限,本质上是保守的,当达到预定的工作极限时,就会淘汰所有部件。这两种方法都使部件在理论上仍有使用寿命的情况下退役。可以使用额外的寿命方法来减少这种保守性并延长这些组件的寿命。美国空军内部开发的因故退役是一种使用寿命的方法,它可以通过仅在有必要时退役组件来延长组件的寿命。审查了有关寿命方法的军事和工业标准。本文讨论了磁盘寿命方法的确定性和概率方法以及当前的工具。本文对政府和工业界目前使用的方法和工具进行了比较。
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引用次数: 2
Carburization effect of Austenitic alloys with various Cr and Al additions under the methane/hydrogen atmosphere on the corrosion behaviors of steels 在甲烷/氢气气氛下,添加不同Cr和Al的奥氏体合金对钢腐蚀行为的渗碳效应
Pub Date : 2021-01-01 DOI: 10.25082/mer.2021.01.005
Shu Liu, J. Cui
The corrosion behaviors of six Fe-19Ni-13/21Cr-xAl (x = 0, 2, 6 at. %) alloys in 10% CH4/H2 at 800oC were investigated. 2 at. % Al did not affect the corrosion resistance obviously, while 6 at. % Al reduced the carbon attack completely for Fe-19Ni-13Cr-6Al but was still insufficient to form protective alumina scales for alloys with 21 at. % Cr. An increase of Cr content changed the appearance of the internal carburization zone under the optical microscope. Stability diagrams of M-C-O system(M= Cr, Fe)were established to estimate the diffusion paths of carbon in the alloys.
研究了6种Fe-19Ni-13/21Cr-xAl (x = 0,2,6 at)的腐蚀行为。在800℃下,对10% CH4/H2中的%)合金进行了研究。2。% Al对合金的耐蚀性影响不明显;% Al完全降低了Fe-19Ni-13Cr-6Al的碳攻击,但仍不足以形成21 at合金的保护性氧化铝鳞片。Cr含量的增加改变了光学显微镜下内部渗碳区的形貌。建立了M- c - o体系(M= Cr, Fe)的稳定性图来估计碳在合金中的扩散路径。
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引用次数: 0
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材料工程研究(英文)
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