Heavy metals and sulfate removal from acid mine drainage using steel mill slag in a rotational mixing device

Nicolás Rojas Arias, Cesar René Blanco-Zuñiga, Carol Natalia Orjuela-Fajardo
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Abstract

The steel mill slag (SMS) production in converter furnaces is one of the main by-products generated during steel production. This waste material is usually composed of different metal oxides that include basic cations such Ca, Mn, and Mg. These cations can favor alkalinity and a heavy metals removal when they are partially dissolved in a contaminant solution such as acid mine drainage (AMD). This work aims to study the potential use of SMS produced in converter furnaces in the mining-steel region of Boyacá- Colombia as an alternative to pre-treat AMD produced by coal mining in the zone. The SMS were separated into two particle sizes by screening, and these were put in contact with AMD samples in a rotational mixing system for 36h. The pH, total Fe (Fe2+, 3+), SO42-, and heavy metals concentration were analyzed at 0h, 12h, 24h, and 36h time intervals. The final results show that SMS produced in the region is an optimal low-cost alternative to treat AMD, allowing complete heavy metals removal in the firsts 12h of treatment. Furthermore, Fe and SO42- removal were observed, reaching 99.9% and 85%, respectively, at 36h. The application of rotational mixing allows complete mixing between AMD and SMS, reducing the possible precipitates adhesion on the surface, limiting the reactivity losses. This mixing treatment device favors a continuous use, avoiding the application of cleaning stages that could be required in the future for optimal functioning.
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在旋转混合装置中用钢渣从酸性矿井排水中去除重金属和硫酸盐
转炉炼钢炉渣是钢铁生产过程中产生的主要副产品之一。这种废料通常由不同的金属氧化物组成,其中包括碱性阳离子,如Ca、Mn和Mg。当这些阳离子部分溶解在酸性矿井排水(AMD)等污染物溶液中时,它们有利于碱度和重金属的去除。这项工作旨在研究哥伦比亚博亚卡钢铁开采区转炉生产的SMS的潜在用途,作为该地区煤矿开采生产的AMD预处理的替代方案。通过筛选将SMS分离成两种粒度,并将其与AMD样品在旋转混合系统中接触36小时。在0小时、12小时、24小时和36小时的时间间隔内分析pH、总Fe(Fe2+、3+)、SO42-和重金属浓度。最终结果表明,该地区生产的SMS是治疗AMD的最佳低成本替代品,可以在治疗的前12小时内完全去除重金属。此外,观察到Fe和SO42-的去除,在36h时分别达到99.9%和85%。旋转混合的应用允许AMD和SMS之间完全混合,减少可能的沉淀物粘附在表面上,限制反应性损失。这种混合处理装置有利于连续使用,避免了未来为实现最佳功能而可能需要的清洁阶段的应用。
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来源期刊
Journal of Applied Research and Technology
Journal of Applied Research and Technology 工程技术-工程:电子与电气
CiteScore
1.50
自引率
0.00%
发文量
0
审稿时长
6-12 weeks
期刊介绍: The Journal of Applied Research and Technology (JART) is a bimonthly open access journal that publishes papers on innovative applications, development of new technologies and efficient solutions in engineering, computing and scientific research. JART publishes manuscripts describing original research, with significant results based on experimental, theoretical and numerical work. The journal does not charge for submission, processing, publication of manuscripts or for color reproduction of photographs. JART classifies research into the following main fields: -Material Science: Biomaterials, carbon, ceramics, composite, metals, polymers, thin films, functional materials and semiconductors. -Computer Science: Computer graphics and visualization, programming, human-computer interaction, neural networks, image processing and software engineering. -Industrial Engineering: Operations research, systems engineering, management science, complex systems and cybernetics applications and information technologies -Electronic Engineering: Solid-state physics, radio engineering, telecommunications, control systems, signal processing, power electronics, electronic devices and circuits and automation. -Instrumentation engineering and science: Measurement devices (pressure, temperature, flow, voltage, frequency etc.), precision engineering, medical devices, instrumentation for education (devices and software), sensor technology, mechatronics and robotics.
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