Operating conditions combination analysis method of optimal water management state for PEM fuel cell

Wenxin Wan , Yang Yang , Yang Li , Changjun Xie , Jie Song , Zhanfeng Deng , Jinting Tan , Ruiming Zhang
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引用次数: 1

Abstract

The water content of proton exchange membrane fuel cells (PEMFCs) affects the transport of reactants and the conductivity of the membrane. Effective water management measures can improve the performance and extend the lifespan of the fuel cell. The water management state of the stack is influenced by various external operating conditions, and optimizing the combination of these conditions can improve the water management state within the stack. Considering that the stack's internal resistance can reflect its water management state, this study first establishes an internal resistance-operating condition model that considers the coupling effect of temperature and humidity to determine the variation trend of total resistance and stack humidity with single-factor operating conditions. Subsequently, the water management state optimization method based on the ANN-HGPSO algorithm is proposed, which not only quantitatively evaluates the influence weights of different operating conditions on the stack's internal resistance but also efficiently and accurately obtains the optimal combination of five operating conditions: working temperature, anode gas pressure, cathode gas pressure, anode gas humidity, and cathode gas humidity to achieve the optimal water management state in the stack, within the entire range of current densities. Finally, the response surface experimental results of the stack also validate the effectiveness and accuracy of the ANN-HGPSO algorithm. The method mentioned in this article can provide effective strategies for efficient water management and output performance optimization control of PEMFC stacks.

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PEM燃料电池最佳水管理状态工况组合分析方法
质子交换膜燃料电池(PEMFC)的含水量影响反应物的传输和膜的导电性。有效的水管理措施可以提高燃料电池的性能并延长其寿命。烟囱的水管理状态受到各种外部操作条件的影响,优化这些条件的组合可以改善烟囱内的水管理状况。考虑到烟囱的内阻可以反映其水管理状态,本研究首先建立了考虑温度和湿度耦合效应的内阻工况模型,以确定总电阻和烟囱湿度在单因素工况下的变化趋势。随后,提出了基于ANN-HGPSO算法的水管理状态优化方法,该方法不仅定量评估了不同操作条件对堆内阻的影响权重,而且高效准确地获得了五种操作条件的最佳组合:工作温度、阳极气压、阴极气压,以在整个电流密度范围内实现堆中的最佳水管理状态。最后,堆栈的响应面实验结果也验证了ANN-HGPSO算法的有效性和准确性。本文中提到的方法可以为PEMFC电池组的高效水管理和输出性能优化控制提供有效的策略。
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