Silicon Oxycarbide Films Produced by Remote Microwave Hydrogen Plasma CVD using a Tetramethyldisiloxane Precursor: Growth Kinetics, Structure, Surface Morphology, and Properties†

Aleksander M. Wrobel, Pawel Uznanski, Agnieszka Walkiewicz-Pietrzykowska
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引用次数: 5

Abstract

Amorphous hydrogenated silicon oxycarbide (a-SiCO:H) thin films are produced by remote microwave hydrogen plasma CVD using 1,1,3,3-tetramethyldisiloxane precursor. The effect of substrate temperature (TS) on the chemical structure and some properties of resulting a-SiCO:H films is reported. The examination performed by infrared spectroscopy revealed that the increase in TS involves the elimination of organic moieties from the film and its transformation from polymer-like to ceramic-like high-crosslink-density material. Due to their small surface roughness, high density, and good optical transparency, the a-SiCO:H films seem to be useful coatings for optical and electronic devices.

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使用四甲基二硅氧烷前驱体的远程微波氢等离子体CVD制备碳化硅氧薄膜:生长动力学,结构,表面形貌和性能
以1,1,3,3-四甲基二硅氧烷为前驱体,采用远程微波氢等离子体气相沉积法制备了非晶氢化碳化硅薄膜。报道了衬底温度对制备的a-SiCO:H薄膜的化学结构和某些性能的影响。红外光谱分析表明,TS的增加涉及到薄膜中有机部分的消除以及其从聚合物样向陶瓷样高交联密度材料的转变。由于其表面粗糙度小,密度高,光学透明度好,a-SiCO:H薄膜似乎是光学和电子器件的有用涂层。
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Chemical Vapor Deposition
Chemical Vapor Deposition 工程技术-材料科学:膜
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期刊介绍: Chemical Vapor Deposition (CVD) publishes Reviews, Short Communications, and Full Papers on all aspects of chemical vapor deposition and related technologies, along with other articles presenting opinion, news, conference information, and book reviews. All papers are peer-reviewed. The journal provides a unified forum for chemists, physicists, and engineers whose publications on chemical vapor deposition have in the past been spread over journals covering inorganic chemistry, materials chemistry, organometallics, applied physics and semiconductor technology, thin films, and ceramic processing.
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