Mechanism of Pollution Control for Aquatic Plant Water Hyacinth

M. Ibrahim, .. Z.I.A.AL-Fifi
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引用次数: 15

Abstract

The aquatic plant water hyacinth is a powerful tool for mediating pollution from aquatic environment. PM3 semiempirical method and FTIR spectroscopy was used to predicate the mechanism of pollution control. First the plant is subjected to acetic acid 0.1 M for 19 hours. FTIR proves that the plant is cellulose like material. Furthermore, the acetylated plant is looks like cellulose acetate. The mechanism of acetylation is tested using PM3 method. CH 3 COOH is interacted with OH of CH 2 OH by two ways. The first is through H-bonding of CH 3 the second is through the interaction of the H-bonding of COOH. The mechanism of divalent metal removal was such that Cd as an example is coordinated with acetylated plant either through two OH of CH 2 OH or through two COOH attached with CH 2 OH.
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水生植物水葫芦污染控制机理研究
水生植物水葫芦是调节水生环境污染的有力工具。采用PM3半经验法和FTIR光谱法对污染控制机理进行了预测。首先将植物置于0.1 M的醋酸中19小时。FTIR证实这种植物是纤维素类物质。此外,乙酰化的植物看起来像醋酸纤维素。用PM3法测试了乙酰化的机理。ch3cooh通过两种途径与ch2oh中的OH相互作用。第一个是通过ch3的氢键第二个是通过COOH的氢键的相互作用。二价金属的脱除机制是这样的,以Cd为例,通过两个ch2oh的OH或通过两个与ch2oh结合的COOH与乙酰化植物配合。
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