Pre-activation of nepheline before the enrichment

IF 0.8 Q4 METALLURGY & METALLURGICAL ENGINEERING Kompleksnoe Ispolzovanie Mineralnogo Syra Pub Date : 2023-04-30 DOI:10.31643/2023/6445.43
Akhmadiyeva Nazym Kanatovna, Abdulvaliyev Rinat Abdulvaliyev, A. Akcil, Manapova Alfiyam
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Abstract

Due to limited reserves of bauxite, nepheline can be used in the industrial production of alumina in Kazakhstan. The most promising deposit is the nepheline syenites of the Kubasadyr deposit. Currently, there is no effective technology for processing nepheline ores. High energy intensity, capital intensity and significant emissions into the atmosphere are the main drawbacks of the conventional technology of nepheline ore processing by sintering method. Efficient hydrochemical processing of nepheline requires pre-enrichment with the separation of a part of silica. According to the existing technology of chemical enrichment in an alkaline solution at a temperature of 280⁰С, the silica extraction degree is no more than 36%. A pre-roasting at 500⁰C is used to increase the extraction rate of silica and this process permits an increase in the extraction rate to 65%. The paper presents the results of the chemical activation of nepheline syenites in a solution of sodium hydrogen carbonate. The optimum conditions of activation are determined. Activation at a temperature of 280 ⁰C resulted in a change in the phase composition of the feedstock and increases the degree of silica extraction up to 65,5%. The results obtained showed the possibility in principle of using hydrochemical enrichment technology for the resulting high-quality nepheline concentrate and replacing the energy-intensive roasting process.
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富集前对霞石进行预活化
由于铝土矿储量有限,霞石可用于哈萨克斯坦氧化铝的工业生产。最有希望的矿床是Kubasadyr矿床的霞石正长岩。目前,还没有有效的霞石矿石加工技术。传统的霞石矿石烧结法加工工艺存在能源强度高、资金强度大、向大气排放大等缺点。霞石的高效水化学处理需要通过分离一部分二氧化硅进行预富集。根据现有的280⁰С温度下碱性溶液化学富集技术,二氧化硅萃取度不大于36%。500℃的预焙烧可以提高二氧化硅的提取率,这一过程可以将提取率提高到65%。本文介绍了霞石正长岩在碳酸氢钠溶液中化学活化的结果。确定了最佳活化条件。在280⁰C的温度下活化导致原料的相组成发生变化,并将二氧化硅的萃取程度提高到65.5%。结果表明,从原理上讲,采用水化学富集技术生产高质量的霞石精矿并取代高能耗的焙烧工艺是可行的。
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