Comparison between Nucleophilicity and Basicity Using the Principle of “Structure Determines Properties”

Xingyu Chen, Xinyu Li, Zhiqian Wang
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Abstract

: This paper provides a practical explanation of the comparison between nucleophilicity and basicity of nucleophiles. The similarities are explained based on the principle of “structure determines property”, and the differences are explained by combining Hard-Soft-Acid-Base theory and the steric hindrance factor.
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用“结构决定性质”原理比较亲核性和碱性
本文对亲核试剂的亲核性和碱度的比较给出了一个实际的解释。根据“结构决定性质”的原理解释其相似性,结合硬-软酸碱理论和位阻因子解释其差异性。
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